百科

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

CAS号：202067-07-0

英文名：(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

分子式：C35H60O6

分子量：576.847

合成路线

(4R,5R)-1-iodo-4,5-isopropylidenedioxy-14-pentadecene

(4R,5R)-1-iodo-4,5-isopropylidenedioxy-14-pentadecene

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(3S,4S)-1-((4R,5R)-5-Dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexane-3,4-diol

(3S,4S)-1-((4R,5R)-5-Dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexane-3,4-diol

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(4R,5R)-4,5-isopropylidenedioxypentadecanol

(4R,5R)-4,5-isopropylidenedioxypentadecanol

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

3-((4R,5R)-5-Decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propionaldehyde

3-((4R,5R)-5-Decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propionaldehyde

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(4R,5R)-4-(3-Benzenesulfonyl-propyl)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolane

(4R,5R)-4-(3-Benzenesulfonyl-propyl)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolane

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

Methanesulfonic acid (1S,2S)-4-((4R,5R)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-[2-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2-methanesulfonyloxy-butyl ester

Methanesulfonic acid (1S,2S)-4-((4R,5R)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-[2-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2-methanesulfonyloxy-butyl ester

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

Benzoic acid 2-benzenesulfonyl-4-((4R,5R)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-[2-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-butyl ester

Benzoic acid 2-benzenesulfonyl-4-((4R,5R)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-[2-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-butyl ester

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

(S)-3-{(E)-(R)-11-Hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undec-2-enyl}-5-methyl-5H-furan-2-one

上游原料

(4R,5R)-4,5-isopropylidenedioxypentadecanol Benzoic acid 2-benzenesulfonyl-4-((4R,5R)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-[2-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-butyl ester Methanesulfonic acid (1S,2S)-4-((4R,5R)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-[2-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2-methanesulfonyloxy-butyl ester (4R,5R)-1-iodo-4,5-isopropylidenedioxy-14-pentadecene (3S,4S)-1-((4R,5R)-5-Dec-9-enyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-((4R,5R)-5-decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexane-3,4-diol 3-((4R,5R)-5-Decyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propionaldehyde (4R,5R)-4-(3-Benzenesulfonyl-propyl)-5-dec-9-enyl-2,2-dimethyl-[1,3]dioxolane

下游产品

(S)-5-Methyl-3-{(2S,3S,11R)-2,3,11-trihydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undecyl}-5H-furan-2-one