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(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

CAS号：203630-42-6

英文名：(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

分子式：C42H68O6Si

分子量：697.071

合成路线

(S)-4-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-pentanal

(S)-4-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-pentanal

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

(2S,3S,4S,5S,6S,9S,10R)-1-Benzyloxy-9-(4-methoxy-benzyloxy)-2,4,6,10-tetramethyl-dodec-11-ene-3,5-diol

(2S,3S,4S,5S,6S,9S,10R)-1-Benzyloxy-9-(4-methoxy-benzyloxy)-2,4,6,10-tetramethyl-dodec-11-ene-3,5-diol

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

81520-08-3

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

(3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol

上游原料

(2S,3S,4S,5S,6S,9S,10R)-1-Benzyloxy-9-(4-methoxy-benzyloxy)-2,4,6,10-tetramethyl-dodec-11-ene-3,5-diol (2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol (S)-4-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-pentanal

下游产品

(4S,5S,6S)-4-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-6-[(1S,4S,5S,6R,7R)-6-methoxy-4-(4-methoxy-benzyloxy)-1,5,7-trimethyl-9-triisopropylsilanyloxy-nonyl]-5-methyl-[1,3,2]dioxasilinane