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(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

CAS号：204572-78-1

英文名：(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

分子式：C71H136O15S2Si5

分子量：1434.39

合成路线

(R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one

(R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(4R,5R)-8-Benzyloxy-4,5-dihydroxy-octanoic acid methyl ester

(4R,5R)-8-Benzyloxy-4,5-dihydroxy-octanoic acid methyl ester

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(4R,5R)-8-Benzyloxy-4,5-dihydroxy-octanoic acid methoxy-amide

(4R,5R)-8-Benzyloxy-4,5-dihydroxy-octanoic acid methoxy-amide

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(4R,5R)-8-Benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-octanoic acid methoxy-amide

(4R,5R)-8-Benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-octanoic acid methoxy-amide

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(E)-(6R,7S,10R,11R)-14-Benzyloxy-1,10,11-tris-(tert-butyl-dimethyl-silanyloxy)-6-(2-trimethylsilanyl-ethoxymethoxy)-tetradec-4-en-7-ol

(E)-(6R,7S,10R,11R)-14-Benzyloxy-1,10,11-tris-(tert-butyl-dimethyl-silanyloxy)-6-(2-trimethylsilanyl-ethoxymethoxy)-tetradec-4-en-7-ol

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

Toluene-4-sulfonic acid (1S,4R,5R)-8-benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(E)-(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hex-2-enyl]-octyl ester

Toluene-4-sulfonic acid (1S,4R,5R)-8-benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(E)-(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hex-2-enyl]-octyl ester

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

Toluene-4-sulfonic acid (1S,4R,5R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hexyl]-8-hydroxy-octyl ester

Toluene-4-sulfonic acid (1S,4R,5R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hexyl]-8-hydroxy-octyl ester

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

Toluene-4-sulfonic acid (1S,4R,5R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hexyl]-8-oxo-octyl ester

Toluene-4-sulfonic acid (1S,4R,5R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hexyl]-8-oxo-octyl ester

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

(8R,9S,12R,13R,16S,17S,23S,E)-23-butyl-12,13-bis((tert-butyldimethylsilyl)oxy)-8-(5-((tert-butyldimethylsilyl)oxy)pentyl)-17-(methoxymethoxy)-2,2,29,29-tetramethyl-5,7,24,26-tetraoxa-2,29-disilatriacont-18-ene-9,16-diyl bis(4-methylbenzenesulfonate)

上游原料

Toluene-4-sulfonic acid (1S,4R,5R)-8-benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(E)-(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hex-2-enyl]-octyl ester Toluene-4-sulfonic acid (1S,4R,5R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hexyl]-8-oxo-octyl ester (R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one (4R,5R)-8-Benzyloxy-4,5-dihydroxy-octanoic acid methyl ester (4R,5R)-8-Benzyloxy-4,5-dihydroxy-octanoic acid methoxy-amide Toluene-4-sulfonic acid (1S,4R,5R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-1-[(R)-6-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-hexyl]-8-hydroxy-octyl ester (4R,5R)-8-Benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-octanoic acid methoxy-amide (E)-(6R,7S,10R,11R)-14-Benzyloxy-1,10,11-tris-(tert-butyl-dimethyl-silanyloxy)-6-(2-trimethylsilanyl-ethoxymethoxy)-tetradec-4-en-7-ol

下游产品

(S)-3-[(R)-13-{(2R,5R,2'R,5'R)-5'-[(1S,7S)-1-Methoxymethoxy-7-(2-trimethylsilanyl-ethoxymethoxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-(2-trimethylsilanyl-ethoxymethoxy)-tridecyl]-5-methyl-5H-furan-2-one bullanin