百科

(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

CAS号：205681-07-8

英文名：(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

分子式：C27H38O4Si

分子量：454.674

合成路线

(1R,3S,5R)-3,5-bis(tert-butyldimethylsilyloxy)-2-methylenecyclohexanol

(1R,3S,5R)-3,5-bis(tert-butyldimethylsilyloxy)-2-methylenecyclohexanol

(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyl-1-methyl-7-oxabicyclo[4.1.0]heptane

(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyl-1-methyl-7-oxabicyclo[4.1.0]heptane

(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

(1S,3R,5R)-3-benzyloxy-1,5-bis(tert-butyldimethylsilyloxy)-2-methylenecyclohexane

(1S,3R,5R)-3-benzyloxy-1,5-bis(tert-butyldimethylsilyloxy)-2-methylenecyclohexane

(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

(2R,5R,7R,9S,10S)-5-benzyloxy-7-(tert-butyldimethylsilyloxy)-2-phenylhexahydrobenzo[1.3]dioxine

上游原料

(1S,3R,5R)-3-benzyloxy-1,5-bis(tert-butyldimethylsilyloxy)-2-methylenecyclohexane (1R,3S,5R)-3,5-bis(tert-butyldimethylsilyloxy)-2-methylenecyclohexanol (1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyl-1-methyl-7-oxabicyclo[4.1.0]heptane

下游产品

(1S,2R,3R,5S)-5-guanin-9-yl-3-benzyloxy-2-(hydroxymethyl)cyclohexanol Benzoic acid (2R,4aS,5R,7S,8aS)-5-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxin-7-yl ester (2R,5R,7R,9S,10S)-7-guanin-9-yl-5-benzyloxy-2-phenylhexahydrobenzo[1.3]dioxine (1S,2R,3R,5S)-5-adenin-9-yl-3-benzyloxy-2-(hydroxymethyl)cyclohexanol (2R,5R,7R,9S,10S)-7-adenin-9-yl-5-benzyloxy-2-phenylhexahydrobenzo[1.3]dioxine (2R,5R,7R,9S,10S)-5-benzyloxy-2-phenylhexahydrobenzo[1.3]dioxin-7-ol