百科

(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

CAS号：205934-53-8

英文名：(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

分子式：C17H22O5

分子量：306.354

合成路线

1,2-O-isopropylidene-5,6-di-O-methanesulfonyl-3-O-(4-methoxybenzyl)-α-D-allofuranose

1,2-O-isopropylidene-5,6-di-O-methanesulfonyl-3-O-(4-methoxybenzyl)-α-D-allofuranose

(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

(R)-1-((3aR,5S,6R,6aR)-6-((4-methoxybenzyl)oxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diyl bis(4-methylbenzenesulfonate)

(R)-1-((3aR,5S,6R,6aR)-6-((4-methoxybenzyl)oxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diyl bis(4-methylbenzenesulfonate)

(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

1,2:5,6-di-O-isopropylidene-3-O-(4-methoxybenzyl)-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-3-O-(4-methoxybenzyl)-α-D-glucofuranose

(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole

上游原料

1,2:5,6-di-O-isopropylidene-3-O-(4-methoxybenzyl)-α-D-glucofuranose 1,2-O-isopropylidene-5,6-di-O-methanesulfonyl-3-O-(4-methoxybenzyl)-α-D-allofuranose (R)-1-((3aR,5S,6R,6aR)-6-((4-methoxybenzyl)oxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diyl bis(4-methylbenzenesulfonate)

下游产品

(2R,3R,4S,5R)-2-Methoxy-4-(4-methoxy-benzyloxy)-5-vinyl-tetrahydro-furan-3-ol (1S,2S,4S,5S)-3-(4-methoxybenzyloxy)cyclooctane-1,2,4,5-tetraol (1S,2S,3R,4S,5S)-3-(4-methoxybenzyloxy)-4-((tert-butyl)dimethylsilyloxy)cyclooctane-1,2,5-triol (1S,2S,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclooctane-1,3-diol (1R,2R,3R)-3-(tert-Butyl-dimethyl-silanyloxy)-cyclooctane-1,2-diol