百科

(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

CAS号：206762-59-6

英文名：(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

分子式：C15H30O4Si

分子量：302.482

合成路线

(+)-S-ethyl (2S,3R)-3-hydroxy-2-methylbutanethioate

(+)-S-ethyl (2S,3R)-3-hydroxy-2-methylbutanethioate

(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

(R,R)-2-[(E)-(benzyloxycarbonyl)vinyl]-2,3-dimethyloxirane

(R,R)-2-[(E)-(benzyloxycarbonyl)vinyl]-2,3-dimethyloxirane

(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

(+)-ethyl (4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenoate

(+)-ethyl (4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenoate

(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

(+)-(4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenyl methyl carbonate

上游原料

(+)-S-ethyl (2S,3R)-3-hydroxy-2-methylbutanethioate (+)-ethyl (4R,5R,E)-5-(tert-butyldimethylsiloxy)-4-methyl-2-hexenoate (R,R)-2-[(E)-(benzyloxycarbonyl)vinyl]-2,3-dimethyloxirane

下游产品

(+)-methyl pederate Benzoic acid methoxycarbonyl-((2R,5R,6R)-2-methoxy-5,6-dimethyl-4-methylene-tetrahydro-pyran-2-yl)-methyl ester methyl (2R,4R,5R,6R)-[5,6-dimethyl-4-(1,3-dithiolan-2-yl)-2-methoxytetrahydropyranyl]-2-O-benzoylglycolate (R)-((2R,4R,5R,6R)-4-[1,3]Dithiolan-2-yl-2-methoxy-5,6-dimethyl-tetrahydro-pyran-2-yl)-hydroxy-acetic acid methyl ester (+)-methyl epi-pederate Benzoic acid methoxycarbonyl-[(2R,4R,5R,6R)-2-methoxy-5,6-dimethyl-4-(2-nitro-phenylselanylmethyl)-tetrahydro-pyran-2-yl]-methyl ester methyl (2R,4R,5R,6R)-[5,6-dimethyl-4-(hydroxymethyl)-2-methoxytetrahydropyranyl]-2-O-benzoylglycolate