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[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

CAS号：207123-34-0

英文名：[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

分子式：C24H38N2O5

分子量：434.569

合成路线

2,2,2-Trichloro-acetimidic acid (2S,3S,5S)-5-methyl-2-vinyl-tetrahydro-furan-3-yl ester

2,2,2-Trichloro-acetimidic acid (2S,3S,5S)-5-methyl-2-vinyl-tetrahydro-furan-3-yl ester

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

(S,S)-2,2-dimethyl-4-[(tert-butyldimethylsilyloxy)methyl]-5-vinyl-1,3-dioxolane

(S,S)-2,2-dimethyl-4-[(tert-butyldimethylsilyloxy)methyl]-5-vinyl-1,3-dioxolane

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

(3S,4S)-Hepta-1,6-diene-3,4-diol

(3S,4S)-Hepta-1,6-diene-3,4-diol

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

(4R,4aS,6S,7aS)-6-Methyl-4-(2,2,6,6-tetramethyl-piperidin-1-yloxymethyl)-2-trichloromethyl-4a,6,7,7a-tetrahydro-4H-furo[2,3-e][1,3]oxazine

(4R,4aS,6S,7aS)-6-Methyl-4-(2,2,6,6-tetramethyl-piperidin-1-yloxymethyl)-2-trichloromethyl-4a,6,7,7a-tetrahydro-4H-furo[2,3-e][1,3]oxazine

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

[(R)-1-((2S,3S,5S)-3-Hydroxy-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester

上游原料

2,2,2-Trichloro-acetimidic acid (2S,3S,5S)-5-methyl-2-vinyl-tetrahydro-furan-3-yl ester (3S,4S)-Hepta-1,6-diene-3,4-diol (S,S)-2,2-dimethyl-4-[(tert-butyldimethylsilyloxy)methyl]-5-vinyl-1,3-dioxolane (4R,4aS,6S,7aS)-6-Methyl-4-(2,2,6,6-tetramethyl-piperidin-1-yloxymethyl)-2-trichloromethyl-4a,6,7,7a-tetrahydro-4H-furo[2,3-e][1,3]oxazine

下游产品

2,5-anhydro-1,3,4,6-tetradeoxy-6-<<(phenylmethoxy)carbonyl>amino>-D-xylo-hept-3-enitol [(R)-1-((2R,5S)-5-Methyl-2,5-dihydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester [(R)-1-((2S,3R,5S)-3-Iodo-5-methyl-tetrahydro-furan-2-yl)-2-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-ethyl]-carbamic acid benzyl ester [(S)-1-((2R,5S)-5-Methyl-2,5-dihydro-furan-2-yl)-2-oxo-ethyl]-carbamic acid benzyl ester (S)-Benzyloxycarbonylamino-((2R,5S)-5-methyl-2,5-dihydro-furan-2-yl)-acetic acid