百科

(3S,6S,7S,8S,12Z,15S,16E)-1,3,7-Trihydroxy-15-[(tert-butyldimethylsilyl)oxy]-4,4,6,8,12,16-hexamethyl-17-(2-methyl-1,3-thiazol-4-yl)-12,16-heptadecadien-5-one

(3S,6S,7S,8S,12Z,15S,16E)-1,3,7-Trihydroxy-15-[(tert-butyldimethylsilyl)oxy]-4,4,6,8,12,16-hexamethyl-17-(2-methyl-1,3-thiazol-4-yl)-12,16-heptadecadien-5-one

CAS号：210691-00-2

英文名：(3S,6S,7S,8S,12Z,15S,16E)-1,3,7-Trihydroxy-15-[(tert-butyldimethylsilyl)oxy]-4,4,6,8,12,16-hexamethyl-17-(2-methyl-1,3-thiazol-4-yl)-12,16-heptadecadien-5-one

分子式：C33H59NO5SSi

分子量：609.976

合成路线

(S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-pentyl-borane

(S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-pentyl-borane

(3S,6S,7S,8S,12Z,15S,16E)-1,3,7-Trihydroxy-15-[(tert-butyldimethylsilyl)oxy]-4,4,6,8,12,16-hexamethyl-17-(2-methyl-1,3-thiazol-4-yl)-12,16-heptadecadien-5-one

(3S,6S,7S,8S,12Z,15S,16E)-1,3,7-Trihydroxy-15-[(tert-butyldimethylsilyl)oxy]-4,4,6,8,12,16-hexamethyl-17-(2-methyl-1,3-thiazol-4-yl)-12,16-heptadecadien-5-one

(4S)-4-[(E)-2-Ethyl-1,1-dimethyl-2-butenyl]-2,2-dimethyl-1,3-dioxane

(4S)-4-[(E)-2-Ethyl-1,1-dimethyl-2-butenyl]-2,2-dimethyl-1,3-dioxane

(3S,6S,7S,8S,12Z,15S,16E)-1,3,7-Trihydroxy-15-[(tert-butyldimethylsilyl)oxy]-4,4,6,8,12,16-hexamethyl-17-(2-methyl-1,3-thiazol-4-yl)-12,16-heptadecadien-5-one

(3S,6S,7S,8S,12Z,15S,16E)-1,3,7-Trihydroxy-15-[(tert-butyldimethylsilyl)oxy]-4,4,6,8,12,16-hexamethyl-17-(2-methyl-1,3-thiazol-4-yl)-12,16-heptadecadien-5-one

上游原料

(S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-pentyl-borane (4S)-4-[(E)-2-Ethyl-1,1-dimethyl-2-butenyl]-2,2-dimethyl-1,3-dioxane

下游产品

(3S,6R,7S,8S,12Z,15S,16E)-1,3,7,15-四-{[叔-丁基(二甲基)硅烷基]氧基}-4,4,6,8,12,16-六甲基-17-(2-甲基-1,3-噻唑-4-基)十七-12,16-二烯-5-酮