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(1S,4S,5S)-5-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-2-oxa-bicyclo[2.2.1]heptan-3-one

(1S,4S,5S)-5-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-2-oxa-bicyclo[2.2.1]heptan-3-one

CAS号：211988-83-9

英文名：(1S,4S,5S)-5-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-2-oxa-bicyclo[2.2.1]heptan-3-one

分子式：C19H34O3Si

分子量：338.557

合成路线

(2S,4S,6R)-6-[((Z,6S)-6-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-heptenyl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]methyl-4-methylbenzenesulfonate

(2S,4S,6R)-6-[((Z,6S)-6-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-heptenyl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]methyl-4-methylbenzenesulfonate

(1S,4S,5S)-5-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-2-oxa-bicyclo[2.2.1]heptan-3-one

(1S,4S,5S)-5-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-2-oxa-bicyclo[2.2.1]heptan-3-one

(Z,8S)-8-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-nonen-2-one

(Z,8S)-8-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-nonen-2-one

(1S,4S,5S)-5-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-2-oxa-bicyclo[2.2.1]heptan-3-one

(1S,4S,5S)-5-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-2-oxa-bicyclo[2.2.1]heptan-3-one

上游原料

(Z,8S)-8-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-nonen-2-one (2S,4S,6R)-6-[((Z,6S)-6-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-heptenyl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]methyl-4-methylbenzenesulfonate

下游产品

(1R,2S,4S)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-(2-methoxy-ethoxymethoxy)-cyclopentanecarbaldehyde