百科

(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

CAS号：213255-06-2

英文名：(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

分子式：C27H33NO5

分子量：451.555

合成路线

(2R,3S)-1,3-Bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-pentan-2-ol

(2R,3S)-1,3-Bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-pentan-2-ol

(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

[(S)-3-Benzyloxy-3-((4S,5R)-4-benzyloxymethyl-5-isopropenyl-2,2-dimethyl-[1,3]dioxan-4-yl)-propoxy]-tert-butyl-dimethyl-silane

[(S)-3-Benzyloxy-3-((4S,5R)-4-benzyloxymethyl-5-isopropenyl-2,2-dimethyl-[1,3]dioxan-4-yl)-propoxy]-tert-butyl-dimethyl-silane

(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

(2R,3S,4S)-4-Benzyloxy-3-benzyloxymethyl-6-(tert-butyl-dimethyl-silanyloxy)-2-isopropenyl-hexane-1,3-diol

(2R,3S,4S)-4-Benzyloxy-3-benzyloxymethyl-6-(tert-butyl-dimethyl-silanyloxy)-2-isopropenyl-hexane-1,3-diol

(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

(5S,5aS,9aR,9bS)-5-Benzyloxy-5a-benzyloxymethyl-7,7,9b-trimethyl-1,5,5a,9,9a,9b-hexahydro-4H-2,6,8-trioxa-3-aza-cyclopenta[a]naphthalene

上游原料

(2R,3S,4S)-4-Benzyloxy-3-benzyloxymethyl-6-(tert-butyl-dimethyl-silanyloxy)-2-isopropenyl-hexane-1,3-diol (2R,3S)-1,3-Bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-pentan-2-ol [(S)-3-Benzyloxy-3-((4S,5R)-4-benzyloxymethyl-5-isopropenyl-2,2-dimethyl-[1,3]dioxan-4-yl)-propoxy]-tert-butyl-dimethyl-silane

下游产品

(1S,2R,3R,4S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-2-hydroxymethyl-3-methyl-7-oxa-bicyclo[4.2.0]octan-1-ol