百科

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

CAS号：213768-14-0

英文名：methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

分子式：C48H60O11

分子量：812.983

合成路线

Methyl 4-O-benzyl-6-O-tert-butyldiphenylsilyl-2,3-di-O-isopropylidene-α-D-mannopyranoside

Methyl 4-O-benzyl-6-O-tert-butyldiphenylsilyl-2,3-di-O-isopropylidene-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

ethyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-1-thio-α-D-galactopyranoside

ethyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-1-thio-α-D-galactopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

Methanesulfonic acid 7-trityloxy-heptyl ester

Methanesulfonic acid 7-trityloxy-heptyl ester

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

(2R,3R,4S,5R,6R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-ethylsulfanyl-tetrahydro-pyran-3,4,5-triol

(2R,3R,4S,5R,6R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-ethylsulfanyl-tetrahydro-pyran-3,4,5-triol

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

ethyl 2,3,4-tri-O-benzyl-6-O-(7'-trityloxyheptyl)-1-thio-α-D-galactopyranoside

ethyl 2,3,4-tri-O-benzyl-6-O-(7'-trityloxyheptyl)-1-thio-α-D-galactopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

methyl 2-O-acetyl-3-O-allyl-4-O-benzyl-α-D-mannopyranoside

methyl 2-O-acetyl-3-O-allyl-4-O-benzyl-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

methyl 2-O-(2',3',4'-tri-O-benzyl-α-D-galactopyranosyl)-4-O-benzyl-6,6'-di-O-(heptane-1,7-diyl)-α-D-mannopyranoside

上游原料

Methyl 4-O-benzyl-6-O-tert-butyldiphenylsilyl-2,3-di-O-isopropylidene-α-D-mannopyranoside Methanesulfonic acid 7-trityloxy-heptyl ester ethyl 2,3,4-tri-O-benzyl-6-O-(7'-trityloxyheptyl)-1-thio-α-D-galactopyranoside ethyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-1-thio-α-D-galactopyranoside (2R,3R,4S,5R,6R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-ethylsulfanyl-tetrahydro-pyran-3,4,5-triol methyl 2-O-acetyl-3-O-allyl-4-O-benzyl-α-D-mannopyranoside

下游产品

(1S,3R,4R,5S,6S,7R,19R,21S,22S,23R)-4,5,6,23-Tetrakis-benzyloxy-22-((2R,3R,5R,6R)-3,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-21-methoxy-2,9,17,20,24-pentaoxa-tricyclo[17.2.2.13,7]tetracosane