百科

(2R,3R,5R)-2-(tert-butyl-dimethyl-silanyloxy)-5,7,7-trimethoxy-3-(4'-methoxy-benzyloxy)-heptan-1-ol

(2R,3R,5R)-2-(tert-butyl-dimethyl-silanyloxy)-5,7,7-trimethoxy-3-(4'-methoxy-benzyloxy)-heptan-1-ol

CAS号：213978-54-2

英文名：(2R,3R,5R)-2-(tert-butyl-dimethyl-silanyloxy)-5,7,7-trimethoxy-3-(4'-methoxy-benzyloxy)-heptan-1-ol

分子式：C24H44O7Si

分子量：472.687

合成路线

3-O-(4'-methoxy-benzyl)-2-deoxy-4,5-O-isopropylidene-D-threo-pentose diethyl dithioacetal

3-O-(4'-methoxy-benzyl)-2-deoxy-4,5-O-isopropylidene-D-threo-pentose diethyl dithioacetal

(2R,3R,5R)-2-(tert-butyl-dimethyl-silanyloxy)-5,7,7-trimethoxy-3-(4'-methoxy-benzyloxy)-heptan-1-ol

(2R,3R,5R)-2-(tert-butyl-dimethyl-silanyloxy)-5,7,7-trimethoxy-3-(4'-methoxy-benzyloxy)-heptan-1-ol

上游原料

3-O-(4'-methoxy-benzyl)-2-deoxy-4,5-O-isopropylidene-D-threo-pentose diethyl dithioacetal

下游产品

(4R,6R)-6-[(2E,4E,8E)-(1R,6R)-9-Bromo-1-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-3-methyl-nona-2,4,8-trienyl]-4-methoxy-tetrahydro-pyran-2-ol (7E,9E,13E)-(3R,5R,6R,11R)-14-Bromo-6-(tert-butyl-dimethyl-silanyloxy)-3,11-dimethoxy-5-(4-methoxy-benzyloxy)-8-methyl-tetradeca-7,9,13-trienal