百科

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

CAS号：214218-32-3

英文名：(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

分子式：C32H50O3Si2

分子量：538.909

合成路线

(-)-(1S)-2-(trimethylsilylmethyl)-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]prop-2-en-1-ol

(-)-(1S)-2-(trimethylsilylmethyl)-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]prop-2-en-1-ol

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

(-)-(2R)-2-methyl-5-[(4R')2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-enoic acid

(-)-(2R)-2-methyl-5-[(4R')2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-enoic acid

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

(+)-(1R)-2-(trimethylsilylmethyl)-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]prop-2-en-1-ol

(+)-(1R)-2-(trimethylsilylmethyl)-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]prop-2-en-1-ol

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

(-)-(1S)-1-[(propanoyl)oxy]-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-2-(trimethylsilylmethyl)prop-2-ene

(-)-(1S)-1-[(propanoyl)oxy]-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-2-(trimethylsilylmethyl)prop-2-ene

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

(+)-(2R)-1-[(tert-butyldiphenylsilyl)oxy]-2-methyl-5-[(4R')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-ene

上游原料

(-)-(1S)-1-[(propanoyl)oxy]-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-2-(trimethylsilylmethyl)prop-2-ene (-)-(2R)-2-methyl-5-[(4R')2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]-4-(trimethylsilylmethyl)pent-4-enoic acid (+)-(1R)-2-(trimethylsilylmethyl)-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]prop-2-en-1-ol (-)-(1S)-2-(trimethylsilylmethyl)-1-[(4S')-2',2',4'-trimethyl-1',3'-dioxolan-4'-yl]prop-2-en-1-ol

下游产品

(-)-(2S,3S,4S,6R)-7-[(tert-butyldiphenylsilyl)oxy]-2,4,6-trimethylheptan-1,3-diol