百科

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

CAS号：214261-07-1

英文名：(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

分子式：C43H54INO3

分子量：759.798

合成路线

214260-99-8

(3S,5E)-6-iodo-3,5-dimethyl-5-hexenal

214261-07-1

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

1027832-48-9

(E)-(S)-1,6-Diiodo-2,4-dimethyl-hex-1-ene

214261-07-1

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

214261-02-6

(6R,8E)-6,8-dimethyl-9-iodo-8-nonenal

214261-07-1

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

214261-01-5

2-((E)-(R)-8-Iodo-5,7-dimethyl-oct-7-enyl)-[1,3]dioxolane

214261-07-1

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

214261-00-4

2-((2E,7E)-(R)-8-Iodo-5,7-dimethyl-octa-2,7-dienyl)-[1,3]dioxolane

214261-07-1

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

214261-03-7

(2E,10E)-(R)-11-Iodo-8,10-dimethyl-undeca-2,10-dienoic acid ethyl ester

214261-07-1

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

214261-04-8

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole-3-carboxylic acid ethyl ester

214261-07-1

(2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-3-[(1,1,1-triphenyl)methoxymethyl]-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole

上游原料

2-((2E,7E)-(R)-8-Iodo-5,7-dimethyl-octa-2,7-dienyl)-[1,3]dioxolane 2-((E)-(R)-8-Iodo-5,7-dimethyl-oct-7-enyl)-[1,3]dioxolane (E)-(S)-1,6-Diiodo-2,4-dimethyl-hex-1-ene (3S,5E)-6-iodo-3,5-dimethyl-5-hexenal (6R,8E)-6,8-dimethyl-9-iodo-8-nonenal (2E,10E)-(R)-11-Iodo-8,10-dimethyl-undeca-2,10-dienoic acid ethyl ester (2R,3R,3aR,4R,4aR,5S,8R,8aS,5'S,7E)-2-(5',7'-dimethyl-8'-iodo-7'-octen-1'-yl)-5,10,10-trimethyl-5,8-methanooctahydro-2H-isoxazolo[3,2-b]benzoxazole-3-carboxylic acid ethyl ester

下游产品

(2E,4E)-(7R,12R,13R)-12-Hydroxy-3,5,7-trimethyl-13-trityloxymethyl-tetradeca-2,4-dienedioic acid 1-tert-butyl ester (2E,4E)-(R)-3,5,7-Trimethyl-11-((2R,3R)-4-oxo-3-trityloxymethyl-oxetan-2-yl)-undeca-2,4-dienoic acid tert-butyl ester