百科

(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

CAS号：214837-05-5

英文名：(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

分子式：C27H45NO6Si

分子量：507.735

合成路线

Isobutyric acid (1R,2S,3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-1-[(E)-1-methyl-2-(2-methyl-oxazol-4-yl)-vinyl]-pentyl ester

Isobutyric acid (1R,2S,3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-1-[(E)-1-methyl-2-(2-methyl-oxazol-4-yl)-vinyl]-pentyl ester

(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

(E)-(2S,4S,5R)-5-Hydroxy-1-(4-methoxy-benzyloxy)-2,4,6-trimethyl-7-(2-methyl-oxazol-4-yl)-hept-6-en-3-one

(E)-(2S,4S,5R)-5-Hydroxy-1-(4-methoxy-benzyloxy)-2,4,6-trimethyl-7-(2-methyl-oxazol-4-yl)-hept-6-en-3-one

(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

Isobutyric acid (1R,2R,3S,4S)-3-hydroxy-5-(4-methoxy-benzyloxy)-2,4-dimethyl-1-[(E)-1-methyl-2-(2-methyl-oxazol-4-yl)-vinyl]-pentyl ester

Isobutyric acid (1R,2R,3S,4S)-3-hydroxy-5-(4-methoxy-benzyloxy)-2,4-dimethyl-1-[(E)-1-methyl-2-(2-methyl-oxazol-4-yl)-vinyl]-pentyl ester

(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

(2E,8E)-(4S,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-isobutyryloxy-4,6,8-trimethyl-9-(2-methyl-oxazol-4-yl)-nona-2,8-dienoic acid methyl ester

上游原料

Isobutyric acid (1R,2S,3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-1-[(E)-1-methyl-2-(2-methyl-oxazol-4-yl)-vinyl]-pentyl ester Isobutyric acid (1R,2R,3S,4S)-3-hydroxy-5-(4-methoxy-benzyloxy)-2,4-dimethyl-1-[(E)-1-methyl-2-(2-methyl-oxazol-4-yl)-vinyl]-pentyl ester (E)-(2S,4S,5R)-5-Hydroxy-1-(4-methoxy-benzyloxy)-2,4,6-trimethyl-7-(2-methyl-oxazol-4-yl)-hept-6-en-3-one

下游产品

{(2R,3S,4S,5S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-[(E)-1-methyl-2-(2-methyl-oxazol-4-yl)-vinyl]-tetrahydro-pyran-2-yl}-acetaldehyde