百科

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

CAS号：215389-04-1

英文名：(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

分子式：C15H20O2

分子量：232.318

合成路线

(1S,4R,5R,6S)-5-[(R)-((1R,6S)-6-Benzyloxy-cyclohex-3-enyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene

(1S,4R,5R,6S)-5-[(R)-((1R,6S)-6-Benzyloxy-cyclohex-3-enyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene

4-Cyclohexene-1,2-diol, (1R,2S)-

4-Cyclohexene-1,2-diol, (1R,2S)-

(1R,6S)-6-Benzyloxy-cyclohex-3-enol

(1R,6S)-6-Benzyloxy-cyclohex-3-enol

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(1S,4R,5R,6S)-5-[(R)-((1R,6S)-6-Benzyloxy-cyclohex-3-enyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene

(1S,4R,5R,6S)-5-[(R)-((1R,6S)-6-Benzyloxy-cyclohex-3-enyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene

(1R,6S)-6-Benzyloxy-cyclohex-3-enol

(1R,6S)-6-Benzyloxy-cyclohex-3-enol

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(1R,2R,3S,4S)-3-methyl-5-norbornene-2-methanol

(1R,2R,3S,4S)-3-methyl-5-norbornene-2-methanol

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(4S,1'R,2'R,3'S,4'S)-3-[(3'-methylbicyclo[2.2.1]hept-5'-ene-2'-yl)carbonyl]-4-iso-propyloxazolidin-2-one

(4S,1'R,2'R,3'S,4'S)-3-[(3'-methylbicyclo[2.2.1]hept-5'-ene-2'-yl)carbonyl]-4-iso-propyloxazolidin-2-one

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(1S,6R)-6-[(R)-Methoxy-((1R,2R,3S,4S)-3-methyl-bicyclo[2.2.1]hept-5-en-2-yl)-methoxy]-cyclohex-3-enol

(1S,6R)-6-[(R)-Methoxy-((1R,2R,3S,4S)-3-methyl-bicyclo[2.2.1]hept-5-en-2-yl)-methoxy]-cyclohex-3-enol

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

(2S,3aS,7aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole

上游原料

(1S,6R)-6-[(R)-Methoxy-((1R,2R,3S,4S)-3-methyl-bicyclo[2.2.1]hept-5-en-2-yl)-methoxy]-cyclohex-3-enol (1S,4R,5R,6S)-5-[(R)-((1R,6S)-6-Benzyloxy-cyclohex-3-enyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene (1R,2R,3S,4S)-3-methyl-5-norbornene-2-methanol (4S,1'R,2'R,3'S,4'S)-3-[(3'-methylbicyclo[2.2.1]hept-5'-ene-2'-yl)carbonyl]-4-iso-propyloxazolidin-2-one

下游产品

(1S,6R)-6-[(R)-Methoxy-((1R,2R,3S,4S)-3-methyl-bicyclo[2.2.1]hept-5-en-2-yl)-methoxy]-cyclohex-3-enol (1R,6S)-6-Benzyloxy-cyclohex-3-enol