百科

(3aS,8R,9R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-6,14,14-trimethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-5(8H)-one

(3aS,8R,9R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-6,14,14-trimethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-5(8H)-one

CAS号：219780-70-8

英文名：(3aS,8R,9R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-6,14,14-trimethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-5(8H)-one

分子式：C39H50O4SSi

分子量：642.962

合成路线

(3aS,8R,9R,13bS)-9-(benzyloxy)-2,6,14,14-tetramethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxaborol-5(8H)-one

(3aS,8R,9R,13bS)-9-(benzyloxy)-2,6,14,14-tetramethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxaborol-5(8H)-one

(3aS,8R,9R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-6,14,14-trimethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-5(8H)-one

(3aS,8R,9R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-6,14,14-trimethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-5(8H)-one

上游原料

(3aS,8R,9R,13bS)-9-(benzyloxy)-2,6,14,14-tetramethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxaborol-5(8H)-one

下游产品

(2S,3aS,5S,9S,9aS,10S,13bS)-6,9a,14,14-tetramethyl-2-phenyl-5,8,9,9a,10,11,12,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-5,9,10,13-tetraol 7-O-(2,2,2-三氯乙氧基羰基)浆果赤霉素 III 紫杉醇