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(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

CAS号：220784-94-1

英文名：(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

分子式：C13H23NO3Si

分子量：269.412

合成路线

(R)-3-Benzyl-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-aza-bicyclo[3.1.0]hexan-1-ol

(R)-3-Benzyl-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-aza-bicyclo[3.1.0]hexan-1-ol

(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

(R)-4-[(Z)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-but-2-enyl]-oxazolidin-2-one

(R)-4-[(Z)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-but-2-enyl]-oxazolidin-2-one

(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

(2R,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-3-hydroxy-3,6-dihydro-2H-pyridine-1-carboxylic acid 2,2,2-trichloro-ethyl ester

(2R,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-3-hydroxy-3,6-dihydro-2H-pyridine-1-carboxylic acid 2,2,2-trichloro-ethyl ester

(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

(8S,8aR)-8-(t-butyldimethylsilyloxy)-8,8a-dihydro-1H-oxazolo[3,4-a]pyridin-3(5H)-one

上游原料

(R)-4-[(Z)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-but-2-enyl]-oxazolidin-2-one (2R,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-3-hydroxy-3,6-dihydro-2H-pyridine-1-carboxylic acid 2,2,2-trichloro-ethyl ester (R)-3-Benzyl-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-aza-bicyclo[3.1.0]hexan-1-ol

下游产品

1-deoxy-L-nojirimycin (1aR,6aR,7S,7aS)-7-hydroxytetrahydro-1aH-oxazolo[3,4-a]oxireno[2,3-d]pyridin-4(2H)-one 1-脱氧野尻霉素