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4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

CAS号：222406-55-5

英文名：4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

分子式：C22H31NO7S2Si

分子量：513.7

合成路线

4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-one

4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-one

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

<4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-ylidene>acetic acid methyl ester

<4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-ylidene>acetic acid methyl ester

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

3a-(2-hydroxyethyl)-4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

3a-(2-hydroxyethyl)-4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

(3aS,4R,6R,7R,7aR)-7-Hydroxy-4-methyl-6-(2-nitro-benzyloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

(3aS,4R,6R,7R,7aR)-7-Hydroxy-4-methyl-6-(2-nitro-benzyloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

<4-methyl-6-(2-nitrobenzyloxy)-2-thioxo-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-3a-yl>acetic acid methyl ester

<4-methyl-6-(2-nitrobenzyloxy)-2-thioxo-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-3a-yl>acetic acid methyl ester

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>-3a-vinyltetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

上游原料

<4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-ylidene>acetic acid methyl ester <4-methyl-6-(2-nitrobenzyloxy)-2-thioxo-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-3a-yl>acetic acid methyl ester 4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-one 3a-(2-hydroxyethyl)-4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione (3aS,4R,6R,7R,7aR)-7-Hydroxy-4-methyl-6-(2-nitro-benzyloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

下游产品

Benzoic acid (S)-2-hydroxy-2-[(2R,3R,4R,5R,6R)-4-hydroxy-2-methyl-3-methylsulfanyl-6-(2-nitro-benzyloxy)-5-(2-trimethylsilanyl-ethoxymethoxy)-tetrahydro-pyran-3-yl]-ethyl ester