百科

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

CAS号：225790-37-4

英文名：(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

分子式：C26H48O2Si2

分子量：448.829

合成路线

(3aS,3bR,4R,6aS)-4-benzyloxy-3,3a,3b,4,5,6,6a,7-octahydro-3a,5,5-trimethylcyclopenta<a>pentalen-2-one

(3aS,3bR,4R,6aS)-4-benzyloxy-3,3a,3b,4,5,6,6a,7-octahydro-3a,5,5-trimethylcyclopenta<a>pentalen-2-one

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3aR,3bS,4S,6aS)-(-)-3,3a,3b,4,5,6,6a,7-octahydro-4-hydroxy-3a,5,5-trimethylcyclopenta<4.5>pentalen-2-one

(3aR,3bS,4S,6aS)-(-)-3,3a,3b,4,5,6,6a,7-octahydro-4-hydroxy-3a,5,5-trimethylcyclopenta<4.5>pentalen-2-one

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-one

5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-one

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(S)-5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-ol

(S)-5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-ol

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-yl chloroacetate

5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-yl chloroacetate

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(S)-3-(benzyloxy)-4,4-dimethyl-2-(methylthio)-1-cyclopentene

(S)-3-(benzyloxy)-4,4-dimethyl-2-(methylthio)-1-cyclopentene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3aS,3bR,4R,6aR)-4-benzyloxy-3,3a,3b,4,5,6,6a,7-octahydro-3a,5,5-trimethyl-1-(methylthio)cyclopenta<a>pentalen-2-one

(3aS,3bR,4R,6aR)-4-benzyloxy-3,3a,3b,4,5,6,6a,7-octahydro-3a,5,5-trimethyl-1-(methylthio)cyclopenta<a>pentalen-2-one

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3aS,3bR,4R,6aR,7aS)-4-Benzyloxy-7a-ethylsulfanyl-3a,5,5-trimethyl-1-methylsulfanyl-decahydro-cyclopenta[a]pentalen-2-one

(3aS,3bR,4R,6aR,7aS)-4-Benzyloxy-7a-ethylsulfanyl-3a,5,5-trimethyl-1-methylsulfanyl-decahydro-cyclopenta[a]pentalen-2-one

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

(3R,3aR,3bS,7aR)-2,2,3b-Trimethyl-5-triisopropylsilanyloxy-3-trimethylsilanyloxy-2,3,3a,3b,4,7a-hexahydro-1H-cyclopenta[a]pentalene

上游原料

(S)-3-(benzyloxy)-4,4-dimethyl-2-(methylthio)-1-cyclopentene (3aS,3bR,4R,6aR,7aS)-4-Benzyloxy-7a-ethylsulfanyl-3a,5,5-trimethyl-1-methylsulfanyl-decahydro-cyclopenta[a]pentalen-2-one (3aS,3bR,4R,6aS)-4-benzyloxy-3,3a,3b,4,5,6,6a,7-octahydro-3a,5,5-trimethylcyclopenta<a>pentalen-2-one (S)-5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-ol 5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-yl chloroacetate (3aR,3bS,4S,6aS)-(-)-3,3a,3b,4,5,6,6a,7-octahydro-4-hydroxy-3a,5,5-trimethylcyclopenta<4.5>pentalen-2-one (3aS,3bR,4R,6aR)-4-benzyloxy-3,3a,3b,4,5,6,6a,7-octahydro-3a,5,5-trimethyl-1-(methylthio)cyclopenta<a>pentalen-2-one 5,5-dimethyl-2-(methylthio)-2-cyclopenten-1-one

下游产品

(3aR,3bS,4S,6aS,7S)-(-)-3,3a,3b,4,5,6,6a,7-octahydro-4,7-dihydroxy-3a,5,5-trimethylcyclopenta<4.5>pentalen-2-one (3aS,3bR,4R,6aS,7S)-3,3a,3b,4,5,6,6a,7-octahydro-3a,5,5-trimethyl-4,7-bis(trimethylsiloxy)lcyclopenta<a>pentalen-2-one