百科

(2R,3S)-3-(2-{(4S,5S)-5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethyl)-oxirane-2-carbaldehyde

(2R,3S)-3-(2-{(4S,5S)-5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethyl)-oxirane-2-carbaldehyde

CAS号：237057-49-7

英文名：(2R,3S)-3-(2-{(4S,5S)-5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethyl)-oxirane-2-carbaldehyde

分子式：C18H34O5Si

分子量：358.545

合成路线

(E)-1-tert-Butyldimethylsilyloxy-6-hydroxy-hex-3-ene

(E)-1-tert-Butyldimethylsilyloxy-6-hydroxy-hex-3-ene

(2R,3S)-3-(2-{(4S,5S)-5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethyl)-oxirane-2-carbaldehyde

(2R,3S)-3-(2-{(4S,5S)-5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethyl)-oxirane-2-carbaldehyde

(3S,4S)-1-Bromo-6-(tert-butyl-dimethyl-silanyloxy)-hexane-3,4-diol

(3S,4S)-1-Bromo-6-(tert-butyl-dimethyl-silanyloxy)-hexane-3,4-diol

(2R,3S)-3-(2-{(4S,5S)-5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethyl)-oxirane-2-carbaldehyde

(2R,3S)-3-(2-{(4S,5S)-5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethyl)-oxirane-2-carbaldehyde

上游原料

(E)-1-tert-Butyldimethylsilyloxy-6-hydroxy-hex-3-ene (3S,4S)-1-Bromo-6-(tert-butyl-dimethyl-silanyloxy)-hexane-3,4-diol

下游产品

16-epi-4,19,23-O-Tris(tert-butyldimethylsilyl)mucocin (2S,3R,6S,1'S)-2-Decyl-3-tert-butyldimethylsilyloxy-6-(1',3'-di-tert-butyldimethylsilyloxy)propyltetrahydropyran 4,19,23-O-Tris(tert-butyldimethylsilyl)mucocin (2S,3R,6S,1'S)-2-Decyl-3-tert-butyldimethylsilyloxy-6-(1'-tert-butyldimethylsilyloxy-3'-hydroxy)-propyl-tetrahydropyran