百科

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

CAS号：239100-47-1

英文名：(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

分子式：C32H64O4Si2

分子量：569.019

合成路线

(1R,3aR,4S,7aR)-7a-methyl-1-[(1S)-1-methyl-1-(phenylsulfonyl)ethyl]-4-(triethylsilyloxy)octahydro-1H-indene

(1R,3aR,4S,7aR)-7a-methyl-1-[(1S)-1-methyl-1-(phenylsulfonyl)ethyl]-4-(triethylsilyloxy)octahydro-1H-indene

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

(8β,24S)-de-A,B-cholesta-8,24,25-triol cyclic 24,25-(1-methylethylidene acetal)

(8β,24S)-de-A,B-cholesta-8,24,25-triol cyclic 24,25-(1-methylethylidene acetal)

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

(1R,3aR,4S,7aR,1S)-4-acetoxy-7a-methyl-1-[(S)-1-methyl-2-(phenylsulphonyl)ethyl]octahydro-1H-indene

(1R,3aR,4S,7aR,1S)-4-acetoxy-7a-methyl-1-[(S)-1-methyl-2-(phenylsulphonyl)ethyl]octahydro-1H-indene

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

(1R,3aR,4S,7aR,1S)-7a-methyl-1-[(1S,2RS,4S)-4,5-dihydroxy-1,5-dimethyl-2-(phenylsulphonyl)hexyl]octahydro-1H-inden-4-ol

(1R,3aR,4S,7aR,1S)-7a-methyl-1-[(1S,2RS,4S)-4,5-dihydroxy-1,5-dimethyl-2-(phenylsulphonyl)hexyl]octahydro-1H-inden-4-ol

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

(1R,3aR,4S,7aR)-4-acetoxy-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-indene

上游原料

(1R,3aR,4S,7aR,1S)-4-acetoxy-7a-methyl-1-[(S)-1-methyl-2-(phenylsulphonyl)ethyl]octahydro-1H-indene (1R,3aR,4S,7aR)-7a-methyl-1-[(1S)-1-methyl-1-(phenylsulfonyl)ethyl]-4-(triethylsilyloxy)octahydro-1H-indene (1R,3aR,4S,7aR,1S)-7a-methyl-1-[(1S,2RS,4S)-4,5-dihydroxy-1,5-dimethyl-2-(phenylsulphonyl)hexyl]octahydro-1H-inden-4-ol (8β,24S)-de-A,B-cholesta-8,24,25-triol cyclic 24,25-(1-methylethylidene acetal)

下游产品

(1R,3aR,4S,7aR)-4-[(E)-bromomethylene]-1-[(1R,4S)-4,5-di(tert-butyldimethylsilyloxy)-1,5-dimethylhexyl]-7a-methyloctahydro-1H-inden 1α,2β,3β-tris(triethylsilyloxy)-24S,25-di(tert-butyldimethylsilyloxy)-9,10-secocholesta-5,7,10(19)-triene