百科

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

CAS号：244217-12-7

英文名：dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

分子式：C19H39O7PSi

分子量：438.568

合成路线

(3S,5R)-7-acetoxy-1-hydroxy-3,5-isopropylidenedioxy-heptane

(3S,5R)-7-acetoxy-1-hydroxy-3,5-isopropylidenedioxy-heptane

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

(4S,6R)-4-(2-(tert-butyldimethylsilyloxy)-ethyl)-6-hydroxyethyl-2,2-dimethyl-1,3-dioxane

(4S,6R)-4-(2-(tert-butyldimethylsilyloxy)-ethyl)-6-hydroxyethyl-2,2-dimethyl-1,3-dioxane

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

{(4S,6S)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid

{(4S,6S)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

(-)-(3S,5R)-7-acetoxy-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-heptane

(-)-(3S,5R)-7-acetoxy-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-heptane

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

dimethyl (+)-(3S,5S)-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-7-oxo-octyl-8-phosphonate

上游原料

(-)-(3S,5R)-7-acetoxy-1-(tert-butyldimethylsilyloxy)-3,5-isopropylidenedioxy-heptane (4S,6R)-4-(2-(tert-butyldimethylsilyloxy)-ethyl)-6-hydroxyethyl-2,2-dimethyl-1,3-dioxane (3S,5R)-7-acetoxy-1-hydroxy-3,5-isopropylidenedioxy-heptane {(4S,6S)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid

下游产品

tert-butyl (-)-(3S,5S,10R,11R)-1-tert-butyldimethylsilyloxy-3,5:10,11-di(isopropylidenedioxy)-7-oxo-tridec-8-en-13-oate tert-butyl (+)-(3S,5R,7S,10R,11R)-1-tert-butyldimethylsilyloxy-7-hydroxy-3,5:10,11-di(isopropylidenedioxy)-tridec-8-en-13-oate