百科

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

CAS号：244770-82-9

英文名：(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

分子式：C29H48O6Si2

分子量：548.859

合成路线

(4R,4aS,10aR)-6,6,8,8-Tetraisopropyl-4,4a,10,10a-tetrahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-4-ol

(4R,4aS,10aR)-6,6,8,8-Tetraisopropyl-4,4a,10,10a-tetrahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-4-ol

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

(2S,3S,4R,4aR,10aR)-2-Allyl-4-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-3-ol

(2S,3S,4R,4aR,10aR)-2-Allyl-4-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-3-ol

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

(4R,4aS,10aR)-4-Benzyloxy-6,6,8,8-tetraisopropyl-4,4a,10,10a-tetrahydro-1,5,7,9-tetraoxa-6,8-disila-benzocyclooctene

(4R,4aS,10aR)-4-Benzyloxy-6,6,8,8-tetraisopropyl-4,4a,10,10a-tetrahydro-1,5,7,9-tetraoxa-6,8-disila-benzocyclooctene

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

(2S,3S,4R,4aR,10aR)-2-Allyl-3-allyloxy-4-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocyclooctene

(2S,3S,4R,4aR,10aR)-2-Allyl-3-allyloxy-4-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocyclooctene

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

(5aS,6aR,12aR,13R,13aS)-13-Benzyloxy-9,9,11,11-tetraisopropyl-2,5,5a,6a,7,12a,13,13a-octahydro-1,6,8,10,12-pentaoxa-9,11-disila-cyclohepta[4,5]benzo[1,2]cyclooctene

上游原料

(2S,3S,4R,4aR,10aR)-2-Allyl-3-allyloxy-4-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocyclooctene (4R,4aS,10aR)-4-Benzyloxy-6,6,8,8-tetraisopropyl-4,4a,10,10a-tetrahydro-1,5,7,9-tetraoxa-6,8-disila-benzocyclooctene (4R,4aS,10aR)-6,6,8,8-Tetraisopropyl-4,4a,10,10a-tetrahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-4-ol (2S,3S,4R,4aR,10aR)-2-Allyl-4-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-3-ol

下游产品

(2S,3S,4R,4aS,9aS)-4-Benzyloxy-2-iodomethyl-3-(4-methoxy-benzyloxy)-3,4,4a,6,9,9a-hexahydro-2H-1,5-dioxa-benzocycloheptene (2R,3R,4S,4aS,9aS)-4-Benzyloxy-2-hydroxymethyl-3,4,4a,6,9,9a-hexahydro-2H-1,5-dioxa-benzocyclohepten-3-ol [(2R,3R,4R,4aS,9aS)-4-Benzyloxy-3-(4-methoxy-benzyloxy)-3,4,4a,6,9,9a-hexahydro-2H-1,5-dioxa-benzocyclohepten-2-yl]-methanol