百科

(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

CAS号：245040-52-2

英文名：(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

分子式：C28H56O4Si2

分子量：512.913

合成路线

(2R,3S)-2-Allyl-4,4-dimethyl-heptane-1,3,5-triol

(2R,3S)-2-Allyl-4,4-dimethyl-heptane-1,3,5-triol

(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

2-[(4S,5R)-5-Allyl-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-2-methyl-pentan-3-one

2-[(4S,5R)-5-Allyl-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-2-methyl-pentan-3-one

(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

(2S,3S)-2-Allyl-3-hydroxy-4,4-dimethyl-1-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-heptane-1,5-dione

(2S,3S)-2-Allyl-3-hydroxy-4,4-dimethyl-1-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-heptane-1,5-dione

(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

(Z)-(3S,4R,9S,10S,11R)-3,10-Bis-(tert-butyl-dimethyl-silanyloxy)-4-hydroxymethyl-2,2,9,11-tetramethyl-cycloundec-6-enone

上游原料

(2S,3S)-2-Allyl-3-hydroxy-4,4-dimethyl-1-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-heptane-1,5-dione (2R,3S)-2-Allyl-4,4-dimethyl-heptane-1,3,5-triol 2-[(4S,5R)-5-Allyl-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-2-methyl-pentan-3-one

下游产品

(Z)-(1S,6S,7S,8R,11S)-7,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6,8,10,10-tetramethyl-9-oxo-cycloundec-3-enecarboxylic acid