百科

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

CAS号：245676-88-4

英文名：(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

分子式：C15H20O5

分子量：280.316

合成路线

(2'R,3'S,2S)-1-[3'-(tert-butyldimethylsiloxy)tetrahydropyran-2'-yl]but-3-en-2-ol

(2'R,3'S,2S)-1-[3'-(tert-butyldimethylsiloxy)tetrahydropyran-2'-yl]but-3-en-2-ol

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2R,3S,2'S)-3-(tert-butyldimethylsiloxy)-2-(2'-methoxy-methoxy-but-3'-enyl)-tetrahydropyran

(2R,3S,2'S)-3-(tert-butyldimethylsiloxy)-2-(2'-methoxy-methoxy-but-3'-enyl)-tetrahydropyran

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(3S,4aR,8aS)-3-(methoxymethoxy)octahydropyrano[3,2-b]pyran-2-ol

(3S,4aR,8aS)-3-(methoxymethoxy)octahydropyrano[3,2-b]pyran-2-ol

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(3S,4aR,8aS)-3-methoxymethoxy-hexahydro-pyrano[3,2-b]pyran-2-one

(3S,4aR,8aS)-3-methoxymethoxy-hexahydro-pyrano[3,2-b]pyran-2-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(3S,4aR,8aS)-2-(((2R,3S)-3-((tert-butyldimethylsilyl)oxy)tetrahydro-2H-pyran-2-yl)ethynyl)-3-(methoxymethoxy)octahydropyrano[3,2-b]pyran-2-ol

(3S,4aR,8aS)-2-(((2R,3S)-3-((tert-butyldimethylsilyl)oxy)tetrahydro-2H-pyran-2-yl)ethynyl)-3-(methoxymethoxy)octahydropyrano[3,2-b]pyran-2-ol

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(3S,4aR,8aS)-2-(((2R,3S)-3-hydroxytetrahydro-2H-pyran-2-yl)ethynyl)-2-methoxyoctahydropyrano[3,2-b]pyran-3-ol

(3S,4aR,8aS)-2-(((2R,3S)-3-hydroxytetrahydro-2H-pyran-2-yl)ethynyl)-2-methoxyoctahydropyrano[3,2-b]pyran-3-ol

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2'R,3'S)-4-[3'-(tert-butyldimethylsiloxy)tetrahydropyran-2'-yl]-2-buten-1-ol

(2'R,3'S)-4-[3'-(tert-butyldimethylsiloxy)tetrahydropyran-2'-yl]-2-buten-1-ol

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,3S,2''R,3''S)-{3-[3''-(tert-butyldimethylsiloxy)tetrahydropyran-2''-yl-methyl]-oxiran-2-yl}-methanol

(2S,3S,2''R,3''S)-{3-[3''-(tert-butyldimethylsiloxy)tetrahydropyran-2''-yl-methyl]-oxiran-2-yl}-methanol

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,3S,2''R,3''S)-p-toluenesulfonic acid 3-[3''-(tert-butyldimethylsiloxy)tetrahydropyran-2''-yl-methyl]-oxiran-2-yl-methyl ester

(2S,3S,2''R,3''S)-p-toluenesulfonic acid 3-[3''-(tert-butyldimethylsiloxy)tetrahydropyran-2''-yl-methyl]-oxiran-2-yl-methyl ester

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(3S,4aR,8aS)-2-((Z)-2-((2R,3S)-3-hydroxytetrahydro-2H-pyran-2-yl)vinyl)-2-methoxyoctahydropyrano[3,2-b]pyran-3-ol

(3S,4aR,8aS)-2-((Z)-2-((2R,3S)-3-hydroxytetrahydro-2H-pyran-2-yl)vinyl)-2-methoxyoctahydropyrano[3,2-b]pyran-3-ol

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

(2S,4aR,8aS,4'aR,8'aS)-spiro(2,4a,6,7,8,8a)-hexahydropyrano[3,2-b]pyrane-2,2'-octahydropyrano[3,2-b]pyran-3'-one

上游原料

(2R,3S,2'S)-3-(tert-butyldimethylsiloxy)-2-(2'-methoxy-methoxy-but-3'-enyl)-tetrahydropyran (3S,4aR,8aS)-2-(((2R,3S)-3-((tert-butyldimethylsilyl)oxy)tetrahydro-2H-pyran-2-yl)ethynyl)-3-(methoxymethoxy)octahydropyrano[3,2-b]pyran-2-ol (2S,3S,2''R,3''S)-p-toluenesulfonic acid 3-[3''-(tert-butyldimethylsiloxy)tetrahydropyran-2''-yl-methyl]-oxiran-2-yl-methyl ester (2S,3S,2''R,3''S)-{3-[3''-(tert-butyldimethylsiloxy)tetrahydropyran-2''-yl-methyl]-oxiran-2-yl}-methanol (2'R,3'S)-4-[3'-(tert-butyldimethylsiloxy)tetrahydropyran-2'-yl]-2-buten-1-ol (3S,4aR,8aS)-3-(methoxymethoxy)octahydropyrano[3,2-b]pyran-2-ol (3S,4aR,8aS)-2-(((2R,3S)-3-hydroxytetrahydro-2H-pyran-2-yl)ethynyl)-2-methoxyoctahydropyrano[3,2-b]pyran-3-ol (2'R,3'S,2S)-1-[3'-(tert-butyldimethylsiloxy)tetrahydropyran-2'-yl]but-3-en-2-ol (3S,4aR,8aS)-3-methoxymethoxy-hexahydro-pyrano[3,2-b]pyran-2-one (3S,4aR,8aS)-2-((Z)-2-((2R,3S)-3-hydroxytetrahydro-2H-pyran-2-yl)vinyl)-2-methoxyoctahydropyrano[3,2-b]pyran-3-ol

下游产品

(4aS,6S,8aR)-6-((R)-1-(2-(2-(allyloxy)ethoxy)ethoxy)-2-((2R,3S)-3-(2-(2-(allyloxy)ethoxy)ethoxy)tetrahydro-2H-pyran-2-yl)ethyl)-2,3,4,4a,6,8a-hexahydropyrano[3,2-b]pyran