百科

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

CAS号：248926-64-9

英文名：methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

分子式：C33H60D4O5Si2

分子量：601.054

合成路线

(Z)-1-iododec-4-en-2-one-7,7,8,8-d4

(Z)-1-iododec-4-en-2-one-7,7,8,8-d4

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

(Z)-1-iododec-4-en-7,7,8,8-d4-2-ol

(Z)-1-iododec-4-en-7,7,8,8-d4-2-ol

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

(E)-4-[(1S,2S,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclopentyl]-but-2-enoic acid methyl ester

(E)-4-[(1S,2S,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclopentyl]-but-2-enoic acid methyl ester

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

(4aS,5S,7R,7aS)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one

(4aS,5S,7R,7aS)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

methyl 4-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate

上游原料

(Z)-1-iododec-4-en-7,7,8,8-d4-2-ol (E)-4-[(1S,2S,3R,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclopentyl]-but-2-enoic acid methyl ester (Z)-1-iododec-4-en-2-one-7,7,8,8-d4 (4aS,5S,7R,7aS)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-hexahydro-cyclopenta[c]pyran-3-one

下游产品

methyl 4-((1S,2R,3R,5S)-3,5-dihydroxy-2-((S,1E,5Z)-3-hydroxyundeca-1,5-dien-1-yl-8,8,9,9-d4)cyclopentyl)butanoate