百科

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

CAS号：250379-10-3

英文名：(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

分子式：C41H58O6Si

分子量：674.981

合成路线

(R)-4-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)-4-hydroxy-N-methoxy-N-methyloctanamide

(R)-4-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)-4-hydroxy-N-methoxy-N-methyloctanamide

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(5R,6S,12R,13S)-12-butyl-13-((tert-butyldiphenylsilyl)oxy)-3,3-diethyl-5-(2-((4-methoxybenzyl)oxy)ethyl)-6,16,16,17,17-pentamethyl-12-((methylthio)methoxy)-4,15-dioxa-3,16-disilaoctadecan-9-one

(5R,6S,12R,13S)-12-butyl-13-((tert-butyldiphenylsilyl)oxy)-3,3-diethyl-5-(2-((4-methoxybenzyl)oxy)ethyl)-6,16,16,17,17-pentamethyl-12-((methylthio)methoxy)-4,15-dioxa-3,16-disilaoctadecan-9-one

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(R)-4-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)-N-methoxy-N-methyl-4-((methylthio)methoxy)octanamide

(R)-4-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)-N-methoxy-N-methyl-4-((methylthio)methoxy)octanamide

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(5R,6S,12R,13S)-12-butyl-13-((tert-butyldiphenylsilyl)oxy)-3,3-diethyl-5-(2-((4-methoxybenzyl)oxy)ethyl)-6,16,16,17,17-pentamethyl-12-((methylthio)methoxy)-4,15-dioxa-3,16-disilaoctadec-7-yn-9-one

(5R,6S,12R,13S)-12-butyl-13-((tert-butyldiphenylsilyl)oxy)-3,3-diethyl-5-(2-((4-methoxybenzyl)oxy)ethyl)-6,16,16,17,17-pentamethyl-12-((methylthio)methoxy)-4,15-dioxa-3,16-disilaoctadec-7-yn-9-one

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-5-((R)-2-butyltetrahydrofuran-2-yl)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecane

(S)-5-((R)-2-butyltetrahydrofuran-2-yl)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecane

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(R)-5-butyl-5-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)dihydrofuran-2(3H)-one

(R)-5-butyl-5-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)dihydrofuran-2(3H)-one

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(R)-4-((S)-1-((tert-butyldiphenylsilyl)oxy)-2-hydroxyethyl)-4-hydroxy-N-methoxy-N-methyloctanamide

(R)-4-((S)-1-((tert-butyldiphenylsilyl)oxy)-2-hydroxyethyl)-4-hydroxy-N-methoxy-N-methyloctanamide

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

(S)-2-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((tert-butyldiphenylsilyl)oxy)ethan-1-ol

上游原料

(R)-4-((S)-1-((tert-butyldiphenylsilyl)oxy)-2-hydroxyethyl)-4-hydroxy-N-methoxy-N-methyloctanamide (R)-5-butyl-5-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)dihydrofuran-2(3H)-one (R)-4-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)-N-methoxy-N-methyl-4-((methylthio)methoxy)octanamide (S)-5-((R)-2-butyltetrahydrofuran-2-yl)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecane (R)-4-((S)-2,2,8,8,9,9-hexamethyl-3,3-diphenyl-4,7-dioxa-3,8-disiladecan-5-yl)-4-hydroxy-N-methoxy-N-methyloctanamide (5R,6S,12R,13S)-12-butyl-13-((tert-butyldiphenylsilyl)oxy)-3,3-diethyl-5-(2-((4-methoxybenzyl)oxy)ethyl)-6,16,16,17,17-pentamethyl-12-((methylthio)methoxy)-4,15-dioxa-3,16-disilaoctadecan-9-one (5R,6S,12R,13S)-12-butyl-13-((tert-butyldiphenylsilyl)oxy)-3,3-diethyl-5-(2-((4-methoxybenzyl)oxy)ethyl)-6,16,16,17,17-pentamethyl-12-((methylthio)methoxy)-4,15-dioxa-3,16-disilaoctadec-7-yn-9-one

下游产品

allyl ((R)-1-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-oxoethyl) succinate allyl ((S)-1-((2R,5S,7R,8S)-2-butyl-7-(2-((4-methoxybenzyl)oxy)ethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-2-((triethylsilyl)oxy)ethyl) succinate