百科

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

CAS号：250379-33-0

英文名：allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

分子式：C51H78O11Si

分子量：895.244

合成路线

(5S,6S)-9,9-diethyl-2,2,3,3,6-pentamethyl-5-((E)-prop-1-en-1-yl)-4,8-dioxa-3,9-disilaundecane

(5S,6S)-9,9-diethyl-2,2,3,3,6-pentamethyl-5-((E)-prop-1-en-1-yl)-4,8-dioxa-3,9-disilaundecane

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-2-butyl-8-methyl-7-(2-oxoethyl)-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-2-butyl-8-methyl-7-(2-oxoethyl)-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

(E)-(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-hex-4-en-1-ol

(E)-(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-hex-4-en-1-ol

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-2-butyl-7-(2-hydroxyethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-2-butyl-7-(2-hydroxyethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

(4R,5S)-4-((tert-butyldimethylsilyl)oxy)-5-methyl-6-((triethylsilyl)oxy)hexane-2,3-diol

(4R,5S)-4-((tert-butyldimethylsilyl)oxy)-5-methyl-6-((triethylsilyl)oxy)hexane-2,3-diol

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate

上游原料

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-2-butyl-8-methyl-7-(2-oxoethyl)-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate (E)-(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-hex-4-en-1-ol (5S,6S)-9,9-diethyl-2,2,3,3,6-pentamethyl-5-((E)-prop-1-en-1-yl)-4,8-dioxa-3,9-disilaundecane allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-2-butyl-7-(2-hydroxyethyl)-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate (4R,5S)-4-((tert-butyldimethylsilyl)oxy)-5-methyl-6-((triethylsilyl)oxy)hexane-2,3-diol

下游产品

allyl ((S,2E,4E)-6-(allyloxy)-1-((2R,5S,7R,8S)-7-((2E,4E,6S,7S,8E)-10-(allyloxy)-6-hydroxy-3,7-dimethyl-10-oxodeca-2,4,8-trien-1-yl)-2-butyl-8-methyl-1,6-dioxaspiro[4.5]decan-2-yl)-4-methyl-6-oxohexa-2,4-dien-1-yl) succinate