百科

(2S,3R,4S,5S,6R)-2-(tert-butyldimethylsilyloxy)-4,6-((R)-benzylidenedioxy)-3,5-dimethylheptanol

(2S,3R,4S,5S,6R)-2-(tert-butyldimethylsilyloxy)-4,6-((R)-benzylidenedioxy)-3,5-dimethylheptanol

CAS号：251099-43-1

英文名：(2S,3R,4S,5S,6R)-2-(tert-butyldimethylsilyloxy)-4,6-((R)-benzylidenedioxy)-3,5-dimethylheptanol

分子式：C22H38O4Si

分子量：394.62

合成路线

(E)-(5S,6S,7R,8S)-8,9-Bis-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-4,5,7-trimethyl-non-3-enoic acid methyl ester

(E)-(5S,6S,7R,8S)-8,9-Bis-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-4,5,7-trimethyl-non-3-enoic acid methyl ester

(2S,3R,4S,5S,6R)-2-(tert-butyldimethylsilyloxy)-4,6-((R)-benzylidenedioxy)-3,5-dimethylheptanol

(2S,3R,4S,5S,6R)-2-(tert-butyldimethylsilyloxy)-4,6-((R)-benzylidenedioxy)-3,5-dimethylheptanol

上游原料

(E)-(5S,6S,7R,8S)-8,9-Bis-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-4,5,7-trimethyl-non-3-enoic acid methyl ester

下游产品

(2R,3S,6S)-3-(tert-Butyl-dimethyl-silanyloxy)-6-{(4S,5R,6R)-6-[(S)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-2-((2R,4S,5S,6R)-5,6-dimethyl-2-phenyl-[1,3]dioxan-4-yl)-heptan-4-ol