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1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

CAS号：251641-60-8

英文名：1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

分子式：C32H54O7Si

分子量：578.852

合成路线

(R)-5-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-pentanoic acid ethyl ester

(R)-5-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-pentanoic acid ethyl ester

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

((2R,4S,6R)-2-Phenyl-6-triisopropylsilanyloxymethyl-[1,3]dioxan-4-yl)-acetaldehyde

((2R,4S,6R)-2-Phenyl-6-triisopropylsilanyloxymethyl-[1,3]dioxan-4-yl)-acetaldehyde

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

(R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hexan-2-one

(R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hexan-2-one

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

(R)-8-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-6-(4-methoxy-benzyloxy)-1-((2R,4R,6R)-2-phenyl-6-triisopropylsilanyloxymethyl-[1,3]dioxan-4-yl)-octan-4-one

(R)-8-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-6-(4-methoxy-benzyloxy)-1-((2R,4R,6R)-2-phenyl-6-triisopropylsilanyloxymethyl-[1,3]dioxan-4-yl)-octan-4-one

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

(R)-5-((tert-butyl)dimethylsilyloxy)-3-(4-methoxybenzyloxy)pentanal

(R)-5-((tert-butyl)dimethylsilyloxy)-3-(4-methoxybenzyloxy)pentanal

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

1-[(2S,4S,6R,8R,10S)-4-Methoxy-10-(4-methoxy-benzyloxy)-8-triisopropylsilanyloxymethyl-1,7-dioxa-spiro[5.5]undec-2-yl]-butan-2-one

上游原料

(R)-8-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-6-(4-methoxy-benzyloxy)-1-((2R,4R,6R)-2-phenyl-6-triisopropylsilanyloxymethyl-[1,3]dioxan-4-yl)-octan-4-one (R)-5-((tert-butyl)dimethylsilyloxy)-3-(4-methoxybenzyloxy)pentanal (R)-5-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-pentanoic acid ethyl ester (R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hexan-2-one ((2R,4S,6R)-2-Phenyl-6-triisopropylsilanyloxymethyl-[1,3]dioxan-4-yl)-acetaldehyde

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