百科

(1S,3R,4S,4aR,8R,8aS)-4-(2S,3aR,6aS)-Hexahydro-furo[2,3-b]furan-2-yl-8a-hydroxymethyl-3,4-dimethyl-8-vinyl-decahydro-naphthalen-1-ol

(1S,3R,4S,4aR,8R,8aS)-4-(2S,3aR,6aS)-Hexahydro-furo[2,3-b]furan-2-yl-8a-hydroxymethyl-3,4-dimethyl-8-vinyl-decahydro-naphthalen-1-ol

CAS号：254752-97-1

英文名：(1S,3R,4S,4aR,8R,8aS)-4-(2S,3aR,6aS)-Hexahydro-furo[2,3-b]furan-2-yl-8a-hydroxymethyl-3,4-dimethyl-8-vinyl-decahydro-naphthalen-1-ol

分子式：C21H34O4

分子量：350.492

合成路线

(3R,4S,4aS,8R,8aS,2'S,3a'R,6a'S)-8a-(tert-butyldimethylsilanyloxymethyl)-4-(hexahydrofuro[2,3-b]furan-2'-yl)-3,4-dimethyloctahydro-8-vinylnaphthalen-1-one

(3R,4S,4aS,8R,8aS,2'S,3a'R,6a'S)-8a-(tert-butyldimethylsilanyloxymethyl)-4-(hexahydrofuro[2,3-b]furan-2'-yl)-3,4-dimethyloctahydro-8-vinylnaphthalen-1-one

(1S,3R,4S,4aR,8R,8aS)-4-(2S,3aR,6aS)-Hexahydro-furo[2,3-b]furan-2-yl-8a-hydroxymethyl-3,4-dimethyl-8-vinyl-decahydro-naphthalen-1-ol

(1S,3R,4S,4aR,8R,8aS)-4-(2S,3aR,6aS)-Hexahydro-furo[2,3-b]furan-2-yl-8a-hydroxymethyl-3,4-dimethyl-8-vinyl-decahydro-naphthalen-1-ol

上游原料

(3R,4S,4aS,8R,8aS,2'S,3a'R,6a'S)-8a-(tert-butyldimethylsilanyloxymethyl)-4-(hexahydrofuro[2,3-b]furan-2'-yl)-3,4-dimethyloctahydro-8-vinylnaphthalen-1-one

下游产品

(1S,3R,4S,4aS,8S,8aS,2'S,3a'R,6a'S)-acetic acid 1-acetoxy-8-bromo-8-formyldecahydro-4-(hexahydrofuro[2,3-b]furan-2'-yl)-3,4-dimethylnaphthalen-8a-ylmethyl ester (4aS,6R,7S,7aR,11aR,2'S,3a'R,6a'S)-7-(hexahydrofuro[2,3-b]furan-2'-yl)-3,3,6,7-tetramethyl-11-methyleneoctahydronaphtho[1,8a-d][1,3]dioxine (4aS,6R,7S,7aR,11S,2'S,3a'R,6a'S)-7-(hexahydrofuro[2,3-b]furan-2'-yl)-3,3,6,7-tetramethyloctahydronaphtho[1,8a-d][1,3]dioxine-11-carbaldehyde