百科

[(1R,2S,4aR,4bS,6aS,11aS,11bR,13aR)-2-(tert-Butyl-dimethyl-silanyloxy)-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-1-yl]-methanol

CAS号：259177-49-6

英文名：[(1R,2S,4aR,4bS,6aS,11aS,11bR,13aR)-2-(tert-Butyl-dimethyl-silanyloxy)-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-1-yl]-methanol

分子式：C34H56O4Si

分子量：556.892

合成路线

259177-47-4

(1R,2S,4aR,4bS,6aS,11aS,11bR,13aR)-9-Allyloxy-1-benzyloxymethyl-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-ol

259177-49-6

[(1R,2S,4aR,4bS,6aS,11aS,11bR,13aR)-2-(tert-Butyl-dimethyl-silanyloxy)-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-1-yl]-methanol

259177-48-5

((1R,2S,4aR,4bS,6aS,11aS,11bR,13aR)-1-Benzyloxymethyl-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-yloxy)-tert-butyl-dimethyl-silane

trifluoro-methanesulfonic acid 1-benzyloxymethyl-2-(tert-butyl-dimethyl-silanyloxy)-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-9-yl ester

259177-49-6

上游原料

((1R,2S,4aR,4bS,6aS,11aS,11bR,13aR)-9-Allyloxy-1-benzyloxymethyl-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-yloxy)-tert-butyl-dimethyl-silane (1R,2S,4aR,4bS,6aS,11aS,11bR,13aR)-9-Allyloxy-1-benzyloxymethyl-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-ol ((1R,2S,4aR,4bS,6aS,11aS,11bR,13aR)-1-Benzyloxymethyl-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-yloxy)-tert-butyl-dimethyl-silane trifluoro-methanesulfonic acid 1-benzyloxymethyl-2-(tert-butyl-dimethyl-silanyloxy)-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-9-yl ester

下游产品

(1S,2S,4aR,4bS,6aS,11aS,11bR,13aR)-2-(tert-Butyl-dimethyl-silanyloxy)-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthrene-1-carbaldehyde Acetic acid (1S,2S,4aR,4bS,6aS,11aS,11bR,13aR)-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-1-[2-((S)-2,6,6-trimethyl-cyclohex-2-enyl)-ethyl]-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-yl ester Acetic acid (1S,2S,4aR,4bS,6aS,11aS,11bR,13aR)-7,10-dihydroxy-1,4a,6a,11b-tetramethyl-1-[2-((S)-2,6,6-trimethyl-cyclohex-2-enyl)-ethyl]-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-yl ester 1-[2-(tert-butyl-dimethyl-silanyloxy)-7,10-dimethoxy-1,4a,6a,11b-tetramethyl-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-1-yl]-2-(2,6,6-trimethyl-cyclohex-2-enyl)-ethanol tert-butyl-{7,10-dimethoxy-1,4a,6a,11b-tetramethyl-1-[2-(2,6,6-trimethyl-cyclohex-2-enyl)-ethyl]-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-yloxy}-dimethyl-silane (1S,2S,4aR,4bS,6aS,11aS,11bR,13aR)-7,10-Dimethoxy-1,4a,6a,11b-tetramethyl-1-[2-((S)-2,6,6-trimethyl-cyclohex-2-enyl)-ethyl]-2,3,4,4a,4b,5,6,6a,11,11a,11b,12,13,13a-tetradecahydro-1H-indeno[2,1-a]phenanthren-2-ol