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(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

CAS号：261967-47-9

英文名：(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

分子式：C30H54O6SSi3

分子量：627.068

合成路线

(2R,3R,4S)-2,3-dihydroxy-5-trityloxy-4-pentanolide

(2R,3R,4S)-2,3-dihydroxy-5-trityloxy-4-pentanolide

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

2,3-bis-O-tert-butyldimethylsilyl-5-O-triphenylmethyl-L-arabino-γ-lactone

2,3-bis-O-tert-butyldimethylsilyl-5-O-triphenylmethyl-L-arabino-γ-lactone

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

(3R,4S,5S)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-hydroxymethyl-dihydro-furan-2-one

(3R,4S,5S)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-hydroxymethyl-dihydro-furan-2-one

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

(3R,4S,5R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-dihydro-furan-2-one

(3R,4S,5R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-dihydro-furan-2-one

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

(4S,5S,6R)-2-Benzenesulfonyl-4,5,6-tris-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone

上游原料

2,3-bis-O-tert-butyldimethylsilyl-5-O-triphenylmethyl-L-arabino-γ-lactone (3R,4S,5S)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-hydroxymethyl-dihydro-furan-2-one (2R,3R,4S)-2,3-dihydroxy-5-trityloxy-4-pentanolide (3R,4S,5R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-dihydro-furan-2-one

下游产品

(1R,4S,5S,6S)-4,5,6-Tris-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclohex-2-enol