百科

(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

CAS号：26293-58-3

英文名：(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

分子式：C13H22O5

分子量：258.311

合成路线

1,2:5,6-di-O-isopropylidene-β-D-arabino-hexofuranos-3-ulose

1,2:5,6-di-O-isopropylidene-β-D-arabino-hexofuranos-3-ulose

(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

3-C-(bromomethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

3-C-(bromomethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

(2S,3R,4R,5R)-5-((R)-1,2-dihydroxyethyl)tetrahydrofuran-2,3,4-triol

(2S,3R,4R,5R)-5-((R)-1,2-dihydroxyethyl)tetrahydrofuran-2,3,4-triol

(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

上游原料

1,2:5,6-di-O-isopropylidene-β-D-arabino-hexofuranos-3-ulose 3-C-(bromomethyl)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

下游产品

(+)-(3aS,4R,5R,6aR)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one (S)-1-((3aR,5S,6R,6aR)-2,2,6-Trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethane-1,2-diol (3aR,5S,6R,6aR)-2,2,6-Trimethyl-5-((E)-1-methyl-propenyl)-tetrahydro-furo[2,3-d][1,3]dioxole 2,4-Dimethylhex-4-en-1,3-diol (4S,5S,6R)-2,2,5-Trimethyl-6-((Z)-2-methylsulfanyl-vinyl)-[1,3]dioxane-4-carbaldehyde (2S,3R,4R)-2,4-Bis-benzyloxymethyl-3-methyl-oxetane Benzoic acid (4S,5R,6R)-6-formyl-2,2,5-trimethyl-[1,3]dioxan-4-ylmethyl ester Toluene-4-sulfonic acid (E)-(2S,3S)-3-hydroxy-2,4-dimethyl-hex-4-enyl ester Toluene-4-sulfonic acid (E)-(2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-hex-4-enyl ester Benzoic acid (4S,5R,6R)-6-(bis-ethylsulfanyl-methyl)-2,2,5-trimethyl-[1,3]dioxan-4-ylmethyl ester tert-Butyl-[(E)-(S)-1-((R)-2-iodo-1-methyl-ethyl)-2-methyl-but-2-enyloxy]-dimethyl-silane (3S,4S,5S)-5-Benzyloxymethyl-3-hydroxy-4-methyl-dihydro-furan-2-one 3-Deoxy-3-C-methyl-D-ribonolactone (3aR,5S,6R,6aR)-2,2,6-Trimethyl-5-((Z)-1-methyl-propenyl)-tetrahydro-furo[2,3-d][1,3]dioxole [(E)-(S)-1-((R)-2-Benzenesulfonyl-1-methyl-ethyl)-2-methyl-but-2-enyloxy]-tert-butyl-dimethyl-silane