百科

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

CAS号：263369-09-1

英文名：3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

分子式：C41H62O6Si2

分子量：707.098

合成路线

methyl (+)-(SR)-3,5-dioxo-6-(p-toluenesulfinyl)hexanoate

methyl (+)-(SR)-3,5-dioxo-6-(p-toluenesulfinyl)hexanoate

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

(4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-tetrahydro-pyran-2-ol

(4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-tetrahydro-pyran-2-ol

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

(+)-(3R,5R)-3-(tert-butyldiphenylsilyloxy)-5-hexanolide

(+)-(3R,5R)-3-(tert-butyldiphenylsilyloxy)-5-hexanolide

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

methyl (+)-(5S,7R,2E)-5-(tert-butyldiphenylsilyloxy)-7-hydroxyoctenoate

methyl (+)-(5S,7R,2E)-5-(tert-butyldiphenylsilyloxy)-7-hydroxyoctenoate

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

3'-methyl-2'-butenyl (+)-(5S,7R,13R,2E,10E)-13-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoate

上游原料

methyl (+)-(5S,7R,2E)-5-(tert-butyldiphenylsilyloxy)-7-hydroxyoctenoate (+)-(3R,5R)-3-(tert-butyldiphenylsilyloxy)-5-hexanolide (4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-tetrahydro-pyran-2-ol methyl (+)-(SR)-3,5-dioxo-6-(p-toluenesulfinyl)hexanoate

下游产品

(+)-(5S,7R,13R,2E,10E)-5-(tert-butyldiphenylsilyloxy)-13-hydroxy-7-methyl-9-oxo-8-oxatetradeca-2,10-dienoic acid