百科

3-[(6R)-5-amino-5-deoxy-1,2-O-isopropylidene-β-D-idofuranos-6C-yl]-1,4-anhydro-3-deoxy-2,6-bis-O-(methoxymethyl)-α-D-galactopyranose

3-[(6R)-5-amino-5-deoxy-1,2-O-isopropylidene-β-D-idofuranos-6C-yl]-1,4-anhydro-3-deoxy-2,6-bis-O-(methoxymethyl)-α-D-galactopyranose

CAS号：263405-70-5

英文名：3-[(6R)-5-amino-5-deoxy-1,2-O-isopropylidene-β-D-idofuranos-6C-yl]-1,4-anhydro-3-deoxy-2,6-bis-O-(methoxymethyl)-α-D-galactopyranose

分子式：C19H33NO11

分子量：451.465

上游原料

(+)-1,4-anhydro-3-{(R)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-3-deoxy-2,6-bis-O-(methoxymethyl)-α-D-galactopyranose

(+)-1,4-anhydro-3-{(R)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-3-deoxy-2,6-bis-O-(methoxymethyl)-α-D-galactopyranose

(-)-(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazole-3-carbaldehyde

(-)-(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazole-3-carbaldehyde

(-)-(1S,2R,3S,4R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aR,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-chloro-2-endo-(methoxymethoxy)-7-oxabicyclo[2.2.1]hept-5-ene

(-)-(1S,2R,3S,4R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aR,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-chloro-2-endo-(methoxymethoxy)-7-oxabicyclo[2.2.1]hept-5-ene

(-)-(1S,2R,3S,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-endo-ol

(-)-(1S,2R,3S,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-endo-ol

(-)-(1S,2R,3R,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-2-endo-(methoxymethoxy)-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]hep...

(-)-(1S,2R,3R,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-2-endo-(methoxymethoxy)-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]hep...

上游原料

(+)-1,4-anhydro-3-{(R)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-3-deoxy-2,6-bis-O-(methoxymethyl)-α-D-galactopyranose (-)-(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazole-3-carbaldehyde (-)-(1S,2R,3S,4R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aR,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-chloro-2-endo-(methoxymethoxy)-7-oxabicyclo[2.2.1]hept-5-ene (-)-(1S,2R,3S,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-endo-ol (-)-(1S,2R,3R,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-2-endo-(methoxymethoxy)-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]hep...