百科

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

CAS号：263543-15-3

英文名：(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

分子式：C26H58O7Si3

分子量：566.991

合成路线

(E,5R,6S,7S,8R,10R)-10-tert-butyldimethylsilyloxy-11-methoxy-5,7-dimethyl-6,8-di(trimethylsilyloxy)-undec-2-en-4-one

(E,5R,6S,7S,8R,10R)-10-tert-butyldimethylsilyloxy-11-methoxy-5,7-dimethyl-6,8-di(trimethylsilyloxy)-undec-2-en-4-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(4R,2'R,4'S,5'R,7'R)-4-benzyl-3-(7'-tert-butyldimethylsilyloxy-5'-hydroxy-8'-methoxy-2',4'-dimethyl-1',3'-dioxooctyl)-1,3-oxazolidin-2-one

(4R,2'R,4'S,5'R,7'R)-4-benzyl-3-(7'-tert-butyldimethylsilyloxy-5'-hydroxy-8'-methoxy-2',4'-dimethyl-1',3'-dioxooctyl)-1,3-oxazolidin-2-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(4R,2'R,3'S,4'S,5'R,7'R)-4-benzyl-3-(7'-tert-butyldimethylsilyloxy-3',5'-dihydroxy-8'-methoxy-2',4'-dimethyl-1'-oxooctyl)-1,3-oxazolidin-2-one

(4R,2'R,3'S,4'S,5'R,7'R)-4-benzyl-3-(7'-tert-butyldimethylsilyloxy-3',5'-dihydroxy-8'-methoxy-2',4'-dimethyl-1'-oxooctyl)-1,3-oxazolidin-2-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(2R,3S,4S,5R,7R)-7-tert-butyldimethylsilyloxy-N,8-dimethoxy-N,2,4-trimethyl-3,5-di(trimethylsilyloxy)octamide

(2R,3S,4S,5R,7R)-7-tert-butyldimethylsilyloxy-N,8-dimethoxy-N,2,4-trimethyl-3,5-di(trimethylsilyloxy)octamide

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(R)-3-(tert-butyldimethylsilyloxy)-4-methoxybutanal

(R)-3-(tert-butyldimethylsilyloxy)-4-methoxybutanal

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

(2S,3R,5R,6S,7S,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-11-methoxy-5,7-dimethyl-6,8-bis-trimethylsilanyloxy-undecan-4-one

上游原料

(4R,2'R,4'S,5'R,7'R)-4-benzyl-3-(7'-tert-butyldimethylsilyloxy-5'-hydroxy-8'-methoxy-2',4'-dimethyl-1',3'-dioxooctyl)-1,3-oxazolidin-2-one (E,5R,6S,7S,8R,10R)-10-tert-butyldimethylsilyloxy-11-methoxy-5,7-dimethyl-6,8-di(trimethylsilyloxy)-undec-2-en-4-one (R)-3-(tert-butyldimethylsilyloxy)-4-methoxybutanal (4R,2'R,3'S,4'S,5'R,7'R)-4-benzyl-3-(7'-tert-butyldimethylsilyloxy-3',5'-dihydroxy-8'-methoxy-2',4'-dimethyl-1'-oxooctyl)-1,3-oxazolidin-2-one (2R,3S,4S,5R,7R)-7-tert-butyldimethylsilyloxy-N,8-dimethoxy-N,2,4-trimethyl-3,5-di(trimethylsilyloxy)octamide

下游产品

(2R,3R,4S,5R,6R,2'R,1''R,2''S)-6-(2'-tert-butyldimethylsilyloxy-3'-methoxypropyl)-2-(1'',2''-dihydroxypropyl)-4-hydroxy-2-methoxy-3,5-dimethyl-2,3,5,6-tetrahydro-4H-pyran