百科

(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

CAS号：264918-94-7

英文名：(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

分子式：C31H48O7Si

分子量：560.794

合成路线

[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl]-methanol

[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl]-methanol

(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

(2R,4aR,6S,7R,9aS)-2-Phenyl-6-vinyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol

(2R,4aR,6S,7R,9aS)-2-Phenyl-6-vinyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol

(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

tert-Butyl-dimethyl-((2R,4aR,7R,9aS)-6-methylene-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-yloxy)-silane

tert-Butyl-dimethyl-((2R,4aR,7R,9aS)-6-methylene-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-yloxy)-silane

(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

(4aS,6R,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-octahydro-1,5-dioxa-benzocycloocten-7-one

上游原料

tert-Butyl-dimethyl-((2R,4aR,7R,9aS)-6-methylene-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-yloxy)-silane [(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl]-methanol (2R,4aR,6S,7R,9aS)-2-Phenyl-6-vinyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol

下游产品

((4aR,6S,7aS,8aR,11S,12R,13aS,14aR,15aS)-11-acetoxy-7a-methoxy-6-methylhexadecahydro-1H-oxepino[2',3':5,6]pyrano[3,2-b]pyrano[2,3-g]oxocin-12-yl)methyl acetate (4aS,6R,9S,10aR)-6-[(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl]-9-methyl-octahydro-1,5-dioxa-benzocycloocten-7-one