百科

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

CAS号：267238-74-4

英文名：(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

分子式：C17H29N3O9

分子量：419.427

合成路线

4,6-O-ethylidene-α-D-glucopyranose

4,6-O-ethylidene-α-D-glucopyranose

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2R,4S,5R,E)-4-(3-butenone-1-yl)-5-hydroxy-2-methyl-1,3-dioxane

(2R,4S,5R,E)-4-(3-butenone-1-yl)-5-hydroxy-2-methyl-1,3-dioxane

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(E)-4-((2R,4S,5R)-5-Methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-but-3-en-2-one

(E)-4-((2R,4S,5R)-5-Methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-but-3-en-2-one

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

tert-Butyl-[(E)-3-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-1-methylene-allyloxy]-dimethyl-silane

tert-Butyl-[(E)-3-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-1-methylene-allyloxy]-dimethyl-silane

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,5S,6R)-5-Azido-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-4-oxo-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,5S,6R)-5-Azido-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-4-oxo-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-3,6-dihydro-2H-pyran-2-carboxylic acid ethyl ester

(2S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-3,6-dihydro-2H-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

(2S,4R,5R,6R)-5-Azido-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester

上游原料

(2R,4S,5R,E)-4-(3-butenone-1-yl)-5-hydroxy-2-methyl-1,3-dioxane (E)-4-((2R,4S,5R)-5-Methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-but-3-en-2-one tert-Butyl-[(E)-3-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-1-methylene-allyloxy]-dimethyl-silane (2S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-3,6-dihydro-2H-pyran-2-carboxylic acid ethyl ester 4,6-O-ethylidene-α-D-glucopyranose (2S,5S,6R)-5-Azido-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-4-oxo-tetrahydro-pyran-2-carboxylic acid ethyl ester

下游产品

(2S,4R,5R,6R)-5-Acetylamino-4-methoxymethoxy-6-((2R,4S,5R)-5-methoxymethoxy-2-methyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-carboxylic acid ethyl ester