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(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

CAS号：267421-75-0

英文名：(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

分子式：C17H26OS

分子量：278.453

合成路线

[1R]-1-methyl-1(3-pentanone)-3-ethylenedioxy-2-oxocyclohexanone

[1R]-1-methyl-1(3-pentanone)-3-ethylenedioxy-2-oxocyclohexanone

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

N-{(R,S)-9-methyl-1,4-dioxaspiro[4.5]decan-8-yliden}-(R)-1-phenylethylamine

N-{(R,S)-9-methyl-1,4-dioxaspiro[4.5]decan-8-yliden}-(R)-1-phenylethylamine

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

(R)-5',8'a-Dimethyl-1',3',4',7',8',8'a-hexahydrospiro[[1,3]-dioxolane-2,2'-naphthalen]-6'-one

(R)-5',8'a-Dimethyl-1',3',4',7',8',8'a-hexahydrospiro[[1,3]-dioxolane-2,2'-naphthalen]-6'-one

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

(R)-5',8'a-Dimethyl-3',4',4'a,7',8',8'a-hexahydro-1'H-spiro[[1,3]dioxolane-2,2'-naphthalene]

(R)-5',8'a-Dimethyl-3',4',4'a,7',8',8'a-hexahydro-1'H-spiro[[1,3]dioxolane-2,2'-naphthalene]

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

(4aR,8aR)-3-[1-Butylsulfanyl-meth-(Z)-ylidene]-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-1H-naphthalen-2-one

上游原料

[1R]-1-methyl-1(3-pentanone)-3-ethylenedioxy-2-oxocyclohexanone (R)-5',8'a-Dimethyl-3',4',4'a,7',8',8'a-hexahydro-1'H-spiro[[1,3]dioxolane-2,2'-naphthalene] N-{(R,S)-9-methyl-1,4-dioxaspiro[4.5]decan-8-yliden}-(R)-1-phenylethylamine (R)-5',8'a-Dimethyl-1',3',4',7',8',8'a-hexahydrospiro[[1,3]-dioxolane-2,2'-naphthalen]-6'-one

下游产品

(3R,4aR,5S,6R,8aR)-5,6-Dihydroxy-3-isopropyl-5,8a-dimethyloctahydronaphthalen-2(1H)-one (1aR,3aR,6R,7aR,7bS)-6-Isopropyl-3a,7b-dimethyloctahydro-1-oxacyclopropa[α]naphthalen-5(1H)-one (3R,4aR,5S,6S,8aR)-5,6-Dihydroxy-3-isopropyl-5,8a-dimethyl-octahydro-naphthalen-2-one