百科

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

CAS号：272767-26-7

英文名：(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

分子式：C15H22O4

分子量：266.333

合成路线

(+/-)-2-methoxyhexahydrofuro[2,3-b]furan

(+/-)-2-methoxyhexahydrofuro[2,3-b]furan

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

(2R,3R,5R,2'R,3a'S,6a'R)-2-(hexahydrofuro[2,3-b]furan-2'-yl)-5-isopropenyl-2,3-dimethylcyclohexanone

(2R,3R,5R,2'R,3a'S,6a'R)-2-(hexahydrofuro[2,3-b]furan-2'-yl)-5-isopropenyl-2,3-dimethylcyclohexanone

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-2,3-dimethyl-5-cyclohexenone

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-2,3-dimethyl-5-cyclohexenone

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

(2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-6-hydroxymethylene-2,3-dimethylcyclohexanone

上游原料

(+/-)-2-methoxyhexahydrofuro[2,3-b]furan (2R,3R,5R,2'R,3a'S,6a'R)-2-(hexahydrofuro[2,3-b]furan-2'-yl)-5-isopropenyl-2,3-dimethylcyclohexanone (2R,3R)-2-[(2R,3aS,6aR)-hexahydrofuro[b]furan-2-yl]-2,3-dimethyl-5-cyclohexenone

下游产品

(6R,7R)-7-[(2R,3aS,6aR)-hexahydrofuro[2,3-b]furan-2-yl]-6,7-dimethyl-4,5,6,7-tetrahydrobenzo[d]isoxazole (1S,3R,4R)-3-[(2R,3aS,6aR)-hexahydrofuro[2,3-b]furan-2-yl]-3,4-dimethyl-2-oxo-cyclohexanecarbonitrile