(Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid

CAS号：279226-53-8

英文名：(Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid

分子式：C46H83NO6SSi3

分子量：862.476

合成路线

279226-52-7

(2S,6Z,9S)-9-(2-methylbenzothiazol-5-yl)-2,6-dimethyl-9-(tert-butyldimethylsilyloxy)-6-nonenal

279226-53-8

(Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid

279226-50-5

5-[(Z)-(1S,8S)-1,9-Bis-(tert-butyl-dimethyl-silanyloxy)-4,8-dimethyl-non-3-enyl]-2-methyl-benzothiazole

279226-53-8

(Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid

279226-51-6

(2S,6Z,9S)-9-(2-methylbenzothiazol-5-yl)-2,6-dimethyl-9-(tert-butyldimethylsilyloxy)-6-nonen-1-ol

279226-53-8

(Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid

279226-64-1

(Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid methyl ester

279226-53-8

(Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid

279227-12-2

(3S,6R,7S,8S)-3,7-bis{[(tert-butyl)dimethylsilyl]oxy}-4,4,6,8-tetramethyl-5-oxoundec-10-enoic acid methyl ester

279226-53-8

(Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid

上游原料

5-[(Z)-(1S,8S)-1,9-Bis-(tert-butyl-dimethyl-silanyloxy)-4,8-dimethyl-non-3-enyl]-2-methyl-benzothiazole (Z)-(3S,6R,7S,8S,15S)-3,7,15-Tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid methyl ester (2S,6Z,9S)-9-(2-methylbenzothiazol-5-yl)-2,6-dimethyl-9-(tert-butyldimethylsilyloxy)-6-nonen-1-ol (2S,6Z,9S)-9-(2-methylbenzothiazol-5-yl)-2,6-dimethyl-9-(tert-butyldimethylsilyloxy)-6-nonenal (3S,6R,7S,8S)-3,7-bis{[(tert-butyl)dimethylsilyl]oxy}-4,4,6,8-tetramethyl-5-oxoundec-10-enoic acid methyl ester

下游产品

(Z)-(4S,7R,8S,9S,16S)-4,8-Bis-(tert-butyl-dimethyl-silanyloxy)-5,5,7,9,13-pentamethyl-16-(2-methyl-benzothiazol-5-yl)-oxacyclohexadec-13-ene-2,6-dione (Z)-(4S,7R,8S,9S,16S)-4,8-Dihydroxy-5,5,7,9,13-pentamethyl-16-(2-methyl-benzothiazol-5-yl)-oxacyclohexadec-13-ene-2,6-dione (Z)-(3S,6R,7S,8S,15S)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-15-hydroxy-4,4,6,8,12-pentamethyl-15-(2-methyl-benzothiazol-5-yl)-5-oxo-pentadec-12-enoic acid