百科

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

CAS号：282107-57-7

英文名：ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

分子式：C38H46O5SSi

分子量：642.919

合成路线

methyl 2,3,5-tri-O-benzoyl-αβ-D-xylbofuranoside

methyl 2,3,5-tri-O-benzoyl-αβ-D-xylbofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

1,2-O-(2,2,2-trichloroethylidene)-β-D-arabinofuranose

1,2-O-(2,2,2-trichloroethylidene)-β-D-arabinofuranose

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

β-D-arabinofuranose 1,2,5-orthodichloroacetate

β-D-arabinofuranose 1,2,5-orthodichloroacetate

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

β-D-arabinofuranose 1,2,5-orthobenzoate

β-D-arabinofuranose 1,2,5-orthobenzoate

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

3-O-benzyl-β-D-arabinofuranose 1,2,5-orthodichloroacetate

3-O-benzyl-β-D-arabinofuranose 1,2,5-orthodichloroacetate

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

3-O-benzyl-β-D-arabinofuranose 1,2,5-orthobenzoate

3-O-benzyl-β-D-arabinofuranose 1,2,5-orthobenzoate

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

ethyl 3-O-benzyl-5-O-tert-butyldiphenylsilyl-2-O-(4-methoxybenzyl)-1-thio-α-D-arabinofuranoside

上游原料

3-O-benzyl-β-D-arabinofuranose 1,2,5-orthobenzoate methyl 2,3,5-tri-O-benzoyl-αβ-D-xylbofuranoside (3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol 1,2-O-(2,2,2-trichloroethylidene)-β-D-arabinofuranose 3-O-benzyl-β-D-arabinofuranose 1,2,5-orthodichloroacetate β-D-arabinofuranose 1,2,5-orthobenzoate β-D-arabinofuranose 1,2,5-orthodichloroacetate

下游产品

9-[4-benzyloxy-3-[[4-benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-2-ethylsulfanyl-tetrahydro-furan-3-yloxy]-(4-methoxy-phenyl)-methoxy]-5-(2,2-dimethyl-propionyloxymethyl)-tetrahydro-furan-2-yloxy]-nonanoic acid methyl ester Benzoic acid (2S,3S,4R,5R)-4-benzyloxy-5-[(2R,3S,4R,5R)-4-benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yloxymethyl]-2-octyloxy-tetrahydro-furan-3-yl ester 8-(methoxycarbonyl)octyl 2-O-(3-O-benzyl-5-O-tert-butyldiphenylsilyl)-β-D-arabinofuranosyl)-3-O-benzyl-5-O-pivaloyl-α-D-arabinofuranoside