百科

methyl (2S,4S,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

methyl (2S,4S,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

CAS号：285556-11-8

英文名：methyl (2S,4S,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

分子式：C16H24N2O9

分子量：388.37

合成路线

(S)-4-((3aS,6R,7R,7aS)-7-Hydroxy-1-methyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-ylmethyl)-2-methoxycarbonylamino-pent-4-enoic acid methyl ester

(S)-4-((3aS,6R,7R,7aS)-7-Hydroxy-1-methyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-ylmethyl)-2-methoxycarbonylamino-pent-4-enoic acid methyl ester

methyl (2S,4S,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

methyl (2S,4S,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

(S)-4-((3aS,6R,7R,7aS)-7-Hydroxy-1-methyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-ylmethyl)-2-methoxycarbonylamino-pent-4-enoic acid methyl ester

(S)-4-((3aS,6R,7R,7aS)-7-Hydroxy-1-methyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-ylmethyl)-2-methoxycarbonylamino-pent-4-enoic acid methyl ester

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

methyl (2S,4S,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

methyl (2S,4S,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

上游原料

(S)-4-((3aS,6R,7R,7aS)-7-Hydroxy-1-methyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-ylmethyl)-2-methoxycarbonylamino-pent-4-enoic acid methyl ester

下游产品

dimethyl (3aS,5aR,5'S,7R,8aR,8bR)-1-methyl-2,2'-dioxooctahydrospiro[furo[2',3':5,6]pyrano[4,3-d]oxazole-7,3'-pyrrolidine]-1',5'-dicarboxylate methyl (2S,3a'S,5a'R,7'R,8aS,8bS)-3-[7'-hydroxymethyl-1'-methyl-2'-oxooctahydro-3',5',8'-trioxa-1'-aza-as-indacen-7'-yl]-2-(methoxycarbonylamino)propionate