百科

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

CAS号：285556-12-9

英文名：methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

分子式：C16H24N2O9

分子量：388.37

合成路线

285556-06-1

(3aS,6R,7R,7aR)-1-methyl-6-(2-oxopropyl)-7-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-2-one

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-09-4

methyl (2S,3a'S,6'R,7'R,7a'S)-2-methoxycarbonylamino-4[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pent-4-enoate

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-04-9

ethyl (4S,4'S,5'S,Z)-4-[5'-(tertbutyldimethylsilyloxy)methyl-3'-methyl-2'-oxooxazolidin-4'-yl]-4-(tert-butyldimethylsilyloxy)but-2-enoate

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-10-7

(S)-4-((3aS,6R,7R,7aS)-7-Hydroxy-1-methyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-ylmethyl)-2-methoxycarbonylamino-pent-4-enoic acid methyl ester

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-11-8

methyl (2S,4S,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-07-2

(3aS,6R,7R,7aR)-1-methyl-7-triethylsilyloxy-6-[(2-trifluoromethanesulfonyloxy)prop-2-enyl]hexahydropyrano[4,3-d]oxazol-2-one

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-00-5

(4R,5S)-4-[(E)-(S)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-5-benzyloxymethyl-oxazolidin-2-one

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-05-0

(3a'S,6'R,7'R,7a'S)-N-methoxy-N-methyl-2-[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]acetamide

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

227627-08-9

(4S,5S,1'S,E)-4-[4'-benzyloxy-1'-(tert-butyldimethylsilyloxy)but-2'-enyl]-5-(benzyloxy)methyl-3-methyloxazolidin-2-one

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-03-8

(R)-(tert-Butyl-dimethyl-silanyloxy)-[(4R,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-2-oxo-oxazolidin-4-yl]-acetaldehyde

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

285556-01-6

(4S,5S,1'S,E)-5-(tert-butyldimethylsilyloxy)methyl-4-[1',4-di(tert-butyldimethylsilyloxy)but-2'-enyl]-3-methyloxazolidin-2-one

285556-12-9

methyl (2S,4R,3a'S,6'R,7'R,7a'S)-4,5-epoxy-2-methoxycarbonylamino-4-[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pentanoate

上游原料

(4S,5R,1'S,E)-4-[4'-benzyloxy-1'-(hydroxy)but-2'-enyl]-5-(benzyloxy)methyloxazolidin-2-one (4S,5S,1'S,E)-4-[4'-benzyloxy-1'-(tert-butyldimethylsilyloxy)but-2'-enyl]-5-(benzyloxy)methyl-3-methyloxazolidin-2-one (S)-4-((3aS,6R,7R,7aS)-7-Hydroxy-1-methyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-ylmethyl)-2-methoxycarbonylamino-pent-4-enoic acid methyl ester (4R,5S)-4-[(E)-(S)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-but-2-enyl]-5-benzyloxymethyl-oxazolidin-2-one (3a'S,6'R,7'R,7a'S)-N-methoxy-N-methyl-2-[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]acetamide (3aS,5aR,8aR,8bS)-1-aza-1-methyl-3,5,8-trioxa-as-hexahydroindacene-2,7-dione (4R,5S,1'S,E)-4-[1'-benzoyloxy-2'-(benzyloxy)ethyl]-5-[3''-(benzyloxy)-prop-1''-enyl]oxazolidin-2-one (R)-(tert-Butyl-dimethyl-silanyloxy)-[(4R,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-2-oxo-oxazolidin-4-yl]-acetaldehyde methyl (2S,3a'S,6'R,7'R,7a'S)-2-methoxycarbonylamino-4[[1'-methyl-2'-oxo-7'-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-6'-yl]methyl]pent-4-enoate ethyl (4S,4'S,5'S,Z)-4-[5'-(tertbutyldimethylsilyloxy)methyl-3'-methyl-2'-oxooxazolidin-4'-yl]-4-(tert-butyldimethylsilyloxy)but-2-enoate (3aS,6R,7R,7aR)-1-methyl-6-(2-oxopropyl)-7-(triethylsilyloxy)hexahydropyrano[4,3-d]oxazol-2-one (4S,5S,1'S,E)-5-(tert-butyldimethylsilyloxy)methyl-4-[1',4-di(tert-butyldimethylsilyloxy)but-2'-enyl]-3-methyloxazolidin-2-one (3aS,6R,7R,7aR)-1-methyl-7-triethylsilyloxy-6-[(2-trifluoromethanesulfonyloxy)prop-2-enyl]hexahydropyrano[4,3-d]oxazol-2-one (4S,5S,1'S,E)-5-(tert-butyldimethylsilyloxy)methyl-4-[4'-chloro-1'-(tert-butyldimethylsilyloxy)but-2'-enyl]-3-methyloxazolidin-2-one (2R,3R,4S,E)-1,7-dibenzyloxy-2,3-epoxy-5-hepten-4-ol

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