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Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

CAS号：286372-54-1

英文名：Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

分子式：C24H38O6

分子量：422.555

合成路线

2,2-Dimethyl-propionic acid (Z)-3-{(4R,5S,6S)-6-[(2E,4E,6E)-(R)-10-(tert-butyl-dimethyl-silanyloxy)-8-methoxy-deca-2,4,6-trienyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-but-2-enyl ester

2,2-Dimethyl-propionic acid (Z)-3-{(4R,5S,6S)-6-[(2E,4E,6E)-(R)-10-(tert-butyl-dimethyl-silanyloxy)-8-methoxy-deca-2,4,6-trienyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

(2E,4E)-(R)-8-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-octa-2,4-dienal

(2E,4E)-(R)-8-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-octa-2,4-dienal

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

(2E,4E)-(R)-8-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-octa-2,4-dien-1-ol

(2E,4E)-(R)-8-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-octa-2,4-dien-1-ol

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

2,2-Dimethyl-propionic acid (Z)-3-{(4R,5S,6S)-6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-but-2-enyl ester

2,2-Dimethyl-propionic acid (Z)-3-{(4R,5S,6S)-6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

(Z)-(5R,6S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-6-trimethylsilanyloxy-oct-2-en-4-ol

(Z)-(5R,6S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-6-trimethylsilanyloxy-oct-2-en-4-ol

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

(Z)-(3S,4S,5R)-1-(tert-Butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-oct-6-ene-3,5-diol

(Z)-(3S,4S,5R)-1-(tert-Butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-oct-6-ene-3,5-diol

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

(Z)-(3S,4S)-1-(tert-Butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-oct-6-ene-3,5-diol

(Z)-(3S,4S)-1-(tert-Butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-oct-6-ene-3,5-diol

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

(4S,5S,6R)-4-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-6-[(Z)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propenyl]-2,2,5-trimethyl-[1,3]dioxane

(4S,5S,6R)-4-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-6-[(Z)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propenyl]-2,2,5-trimethyl-[1,3]dioxane

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

(Z)-(5S,6S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-3,5-dimethyl-oct-2-en-4-one

(Z)-(5S,6S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-3,5-dimethyl-oct-2-en-4-one

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

tert-Butyl-((E)-(R)-5-iodo-3-methoxy-pent-4-enyloxy)-dimethyl-silane

tert-Butyl-((E)-(R)-5-iodo-3-methoxy-pent-4-enyloxy)-dimethyl-silane

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

Acetic acid (Z)-3-[(4R,5S,6S)-6-((2E,4E,6E)-(R)-10-hydroxy-8-methoxy-deca-2,4,6-trienyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester

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上游原料

(Z)-3-{(4R,5S,6S)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-but-2-en-1-ol (2S,3S)-5-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-3-trimethylsilanyloxy-pentanal 2,2-Dimethyl-propionic acid (Z)-3-[(4R,5S,6S)-6-(2-hydroxy-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-but-2-enyl ester (Z)-3-{(4R,5S,6S)-6-[(2E,4E,6E)-(R)-10-(tert-Butyl-dimethyl-silanyloxy)-8-methoxy-deca-2,4,6-trienyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-but-2-en-1-ol tert-Butyl-((E)-(R)-5-iodo-3-methoxy-pent-4-enyloxy)-dimethyl-silane 2,2-Dimethyl-propionic acid (Z)-3-{(4R,5S,6S)-6-[(2E,4E,6E)-(R)-10-(tert-butyl-dimethyl-silanyloxy)-8-methoxy-deca-2,4,6-trienyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-but-2-enyl ester (Z)-(5S,6S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-3,5-dimethyl-oct-2-en-4-one (Z)-(5R,6S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-6-trimethylsilanyloxy-oct-2-en-4-ol (Z)-(3S,4S,5R)-1-(tert-Butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-oct-6-ene-3,5-diol 2,2-Dimethyl-propionic acid (Z)-3-{(4R,5S,6S)-2,2,5-trimethyl-6-[2-(1-phenyl-1H-tetrazol-5-ylsulfanyl)-ethyl]-[1,3]dioxan-4-yl}-but-2-enyl ester (4S,5S,6R)-4-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-6-[(Z)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propenyl]-2,2,5-trimethyl-[1,3]dioxane (2E,4E)-(R)-8-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-octa-2,4-dien-1-ol (2E,4E)-(R)-8-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-octa-2,4-dienal 2,2-Dimethyl-propionic acid (Z)-3-{(4R,5S,6S)-6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-but-2-enyl ester (Z)-(3S,4S)-1-(tert-Butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-oct-6-ene-3,5-diol (3R,4S)-6-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-4-trimethylsilanyloxy-hex-1-ene

下游产品

(4E,6E,8E)-(R)-10-[(4S,5S,6R)-6-((Z)-3-Chloro-1-methyl-propenyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-3-methoxy-deca-4,6,8-trienoic acid methyl ester (4E,6E,8E)-(R)-10-[(4S,5S,6R)-6-((Z)-3-Acetoxy-1-methyl-propenyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-3-methoxy-deca-4,6,8-trienoic acid methyl ester