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Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

CAS号：286409-15-2

英文名：Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

分子式：C11H18O6S

分子量：278.322

合成路线

(+)-(1S,2R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

(+)-(1S,2R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

(1R,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-one

(1R,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-one

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

(+)-(1R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-4-vinyl-6,8-dioxabicyclo[3.2.1]oct-2-one

(+)-(1R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-4-vinyl-6,8-dioxabicyclo[3.2.1]oct-2-one

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

上游原料

(+)-(1R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-4-vinyl-6,8-dioxabicyclo[3.2.1]oct-2-one (1R,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-one (+)-(1S,2R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

下游产品

(+)-(1S,2R,4S,5R,7S)-7-iodomethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane (3S,5R,6R)-5-Methoxy-3,6-divinyl-tetrahydro-pyran-2-ol (+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene (1R,4S,6R)-4-Hydroxymethyl-6-methoxy-cyclohex-2-enol (-)-(1R,2R,4R)-4-hydroxymethyl-2-methoxycyclohexan-1-ol