百科

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

CAS号：286409-18-5

英文名：(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

分子式：C10H18O3

分子量：186.248

合成路线

(+)-(1S,2R,4S,5R,7S)-7-iodomethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

(+)-(1S,2R,4S,5R,7S)-7-iodomethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(1S,2R,4S,5R,7S)-7-hydroxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

(+)-(1S,2R,4S,5R,7S)-7-hydroxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(1S,2R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

(+)-(1S,2R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(3S,5R,6R)-5-Methoxy-3,6-divinyl-tetrahydro-pyran-2-ol

(3S,5R,6R)-5-Methoxy-3,6-divinyl-tetrahydro-pyran-2-ol

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(1R,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-one

(1R,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-one

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(1R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-4-vinyl-6,8-dioxabicyclo[3.2.1]oct-2-one

(+)-(1R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-4-vinyl-6,8-dioxabicyclo[3.2.1]oct-2-one

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

(+)-(3R,4R,6S)-3-hydroxy-6-hydroxymethyl-4-methoxy-1,7-octadiene

上游原料

Methanesulfonic acid (1S,2R,4S,5R,7S)-2-methoxy-4-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethyl ester (+)-(1S,2R,4S,5R,7S)-7-iodomethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane (+)-(1R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-4-vinyl-6,8-dioxabicyclo[3.2.1]oct-2-one (3S,5R,6R)-5-Methoxy-3,6-divinyl-tetrahydro-pyran-2-ol (1R,5R,7S)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-one (+)-(1S,2R,4S,5R,7S)-7-tert-butyldimethylsiloxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane (+)-(1S,2R,4S,5R,7S)-7-hydroxymethyl-2-methoxy-4-vinyl-6,8-dioxabicyclo[3.2.1]octane

下游产品

(1R,4S,6R)-4-Hydroxymethyl-6-methoxy-cyclohex-2-enol (-)-(1R,2R,4R)-4-hydroxymethyl-2-methoxycyclohexan-1-ol