百科

(2R,5S,6S,9R)-1,2;9,10-di-O-isopropylidene-1,2,9,10-tetraol 5,6-bis-p-toluenesulfonate

(2R,5S,6S,9R)-1,2;9,10-di-O-isopropylidene-1,2,9,10-tetraol 5,6-bis-p-toluenesulfonate

CAS号：286853-87-0

英文名：(2R,5S,6S,9R)-1,2;9,10-di-O-isopropylidene-1,2,9,10-tetraol 5,6-bis-p-toluenesulfonate

分子式：C30H42O10S2

分子量：626.778

合成路线

(4R)-4-(but-3-yn-1-yl)-2,2-dimethyl-1,3-dioxolane

(4R)-4-(but-3-yn-1-yl)-2,2-dimethyl-1,3-dioxolane

(2R,5S,6S,9R)-1,2;9,10-di-O-isopropylidene-1,2,9,10-tetraol 5,6-bis-p-toluenesulfonate

(2R,5S,6S,9R)-1,2;9,10-di-O-isopropylidene-1,2,9,10-tetraol 5,6-bis-p-toluenesulfonate

(2R,9R)-1,2;9,10-di-O-isopropylidene-5-decyne-1,2,9,10-tetraol

(2R,9R)-1,2;9,10-di-O-isopropylidene-5-decyne-1,2,9,10-tetraol

(2R,5S,6S,9R)-1,2;9,10-di-O-isopropylidene-1,2,9,10-tetraol 5,6-bis-p-toluenesulfonate

(2R,5S,6S,9R)-1,2;9,10-di-O-isopropylidene-1,2,9,10-tetraol 5,6-bis-p-toluenesulfonate

上游原料

(2R,9R)-1,2;9,10-di-O-isopropylidene-5-decyne-1,2,9,10-tetraol (4R)-4-(but-3-yn-1-yl)-2,2-dimethyl-1,3-dioxolane

下游产品

(2'R,2''R,5'R, 5R'')-[5'-(5''-(tert-butyldimethylsilyloxy)methyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]carbaldehyde (2R,2R',5R, 5R')-[5-(5'-(tert-butyldimethylsilyloxy)methyltetrahydrofuran-2'-yl)tetrahydrofuran-2-yl]methanol (2R',2''R,5'R,5''R)-1-[5'-(5''-(tert-butyldimethylsilyloxy)methyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-15-benzyloxypentadecan-1-one (1R,2R,2'R,5R,5R')-1-[5-(5'-(tert-butyldimethylsilyloxy)methyltetrahydrofuran-2'-yl)tetrahydrofuran-2-yl]-15-benzyloxypentadecan-1-ol (1R,2'R,2''R,5'R,5''R)-1-[5'-(5''-(tert-butyldimethylsilyloxy)methyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-1-(tert-butyldimethylsilyloxy)-15-benzyloxypentadecan-1-one